334235

(3S-cis)-(+)-3-Isopropyl-7a-methyltetrahydropyrrolo[2,1-b]oxazol-5(6H)-on

95%

• Empirische Formel (Hill-System): C₁₀H₁₇NO₂
• CAS-Nummer: 98203-44-2
• Molekulargewicht: 183.25
• MDL-Nummer: MFCD00467212
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24860069

Eigenschaften

• Assay: 95%
• Form: liquid
• Optische Aktivität: [α]27/D +90°, c = 2.8 in ethanol
• Brechungsindex: n20/D 1.473 (lit.)
• bp: 70 °C/0.4 mmHg (lit.)
• Dichte: 1.027 g/mL at 25 °C (lit.)
• SMILES String: CC(C)[C@H]1CO[C@]2(C)CCC(=O)N12
• InChI: 1S/C10H17NO2/c1-7(2)8-6-13-10(3)5-4-9(12)11(8)10/h7-8H,4-6H2,1-3H3/t8-,10-/m1/s1
• InChIKey: NUUDVADIQSLTCN-PSASIEDQSA-N

Beschreibung

Anwendung

Chiral bicyclic lactams such as this are useful templates for the asymmetric synthesis of a variety of natural and unnatural products. High levels of asymmetric induction have been obtained in cycloadditions, alkylations, conjugate additions, annulations, and dihydroxylations.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P261 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 136.4 °F - closed cup
• Flammpunkt (°C): 58 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter