275913

Tricarbonyl(cyclooctatetraen)eisen(II)

98%

• Synonym(e): 1,3,5,7-Cyclooctatetraeneiron tricarbonyl, Cyclooctatetraenetricarbonyliron, NSC 167370, NSC 168049
• Lineare Formel: C₈H₈Fe(CO)₃
• CAS-Nummer: 12093-05-9
• Molekulargewicht: 244.02
• MDL-Nummer: MFCD00001755
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24856681
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: solid
• Eignung der Reaktion: core: iron; reagent type: catalyst
• mp (Schmelzpunkt): 93-95 °C (lit.)
• SMILES String: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=CC=C1
• InChI: 1S/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1-,4-2-,5-3-,6-4-,7-5-,8-6-,8-7-;;;;
• InChIKey: XAOCYVWRKJTXOL-CJNMVQMASA-N

Beschreibung

Anwendung

Catalyst for:

• Light-driven hydrogen generation via reduction of water
• Growth of multiwalled carbon nanotubes
• Tandem isomerization-aldol condensation of allylic alcohols
• Hydrogenation of anthracene and nitrogen heterocycles under water-gas shift conditions

Used:

• For VPE-growth of iron-doped indium phosphide by metal organic chemical vapor deposition (MOCVD)
• As sensitizer for isomerization of norbornadiene in solar-energy storage

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H302 + H312 + H332
• P-Sätze: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Oral
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves