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Merck

205737

Sigma-Aldrich

Palladium auf Calciumcarbonat

greener alternative

extent of labeling: 5 wt. % loading, poisoned with lead

Synonym(e):

Pd

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About This Item

Lineare Formel:
Pd
MDL-Nummer:
UNSPSC-Code:
12141733
eCl@ss:
38191001
PubChem Substanz-ID:
NACRES:
NA.22

Form

powder

Selbstzündungstemp.

>1120 °F

Eignung der Reaktion

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Kennzeichnungsgrad

5 wt. % loading

Grünere Alternativprodukt-Kategorie

SMILES String

[Ca++].[Pd++].[O-]C([O-])=O.[O-]C([O-])=O

InChI

1S/2CH2O3.Ca.Pd/c2*2-1(3)4;;/h2*(H2,2,3,4);;/q;;2*+2/p-4

InChIKey

XGLHAVVVUOEGIO-UHFFFAOYSA-J

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Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Catalyst for:
  • Aqueous Heck coupling and hydroarylation
  • Reduction reactions
  • Hydrogenation reactions
Palladium on calcium carbonate (Pd/CaCO3) can be used as a green catalyst for a variety of applications such as:
  • formation of an efficient catalytic system for Heck coupling reaction and hydroarylation reaction
  • synthesis of Lindlar catalyst for selective hydrogenation of alkynes
  • a catalytic reservoir in Miyaura-Suzuki cross-coupling reactions
  • Stille cross-coupling reactions

Piktogramme

Health hazardEnvironment

Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 1 - Lact. - Repr. 1A - STOT RE 2

Zielorgane

Central nervous system,Blood,Immune system,Kidney

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Ligand-free Stille cross-coupling reaction using Pd/CaCO3 as catalyst reservoir
Coelho AV, et al.
Tetrahedron Letters, 48(43), 7671-7674 (2007)
Miyaura-Suzuki cross-coupling reactions: the role of Pd/CaCO3 as catalyst reservoir
Oliveira BL and Antunes OAC
Letters in Organic Chemistry, 4(1), 13-15 (2007)
Palladium on Calcium Carbonate Combined to 2-Hydroxypropyl-alpha/beta-cyclodextrins: A Selective Catalytic System for Aqueous Heck Coupling and Hydroarylation
Senra JD, et al.
Advanced Synthesis & Catalysis, 350(16), 2551-2558 (2008)
Palladium on Calcium Carbonate Combined to 2-Hydroxypropyl-alpha/beta-cyclodextrins: A Selective Catalytic System for Aqueous Heck Coupling and Hydroarylation
Senra JD, et al.
advanced synthesis and catalysis, 350(16), 2551-2558 (2008)
Chun Wong Aaron Chan et al.
Nature communications, 5, 5787-5787 (2014-12-20)
Lindlar catalysts comprising of palladium/calcium carbonate modified with lead acetate and quinoline are widely employed industrially for the partial hydrogenation of alkynes. However, their use is restricted, particularly for food, cosmetic and drug manufacture, due to the extremely toxic nature

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