155039

Diphenyl(p-tolyl)phosphin

96%

• Synonym(e): (4-Methylphenyl)diphenyl phosphine
• Lineare Formel: (C₆H₅)₂PC₆H₄CH₃
• CAS-Nummer: 1031-93-2
• Molekulargewicht: 276.31
• EG-Nummer: 213-848-3
• MDL-Nummer: MFCD00008543
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24849330
• NACRES: NA.22

Eigenschaften

• Assay: 96%
• Form: liquid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp (Schmelzpunkt): 66-68 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: Cc1ccc(cc1)P(c2ccccc2)c3ccccc3
• InChI: 1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
• InChIKey: QJIMTLTYXBDJFC-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Three-component cyclization
• Probing coordination ability via a palladium pincer complex
• Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:

• Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
• Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
• InP nanofibers / metal phosphide nanostructures
• Peroxyl radical cations via pulse radiolysis one-electron oxidations

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves