71210

Sodium ethoxide

≥95% (T), powder, technical

• Synonym(s): Sodium ethylate
• Linear Formula: CH₃CH₂ONa
• CAS Number: 141-52-6
• Molecular Weight: 68.05
• NACRES: NA.21
• PubChem Substance ID: 329763111
• UNSPSC Code: 12352100
• EC Number: 205-487-5
• MDL number: MFCD00012417
• Beilstein/REAXYS Number: 3593646
• Assay: ≥95% (T)
• Form: powder

Properties

• Product Name: Sodium ethoxide, technical, ≥95% (T)
• vapor density: 1.6 (vs air)
• Quality Segment: 100
• vapor pressure: <0.1 mmHg ( 20 °C)
• grade: technical
• assay: ≥95% (T)
• form: powder
• impurities: ~2% Na₂CO₃ and NaOH
• SMILES string: [Na+].CC[O-]
• InChI: 1S/C2H5O.Na/c1-2-3;/h2H2,1H3;/q-1;+1
• InChI key: QDRKDTQENPPHOJ-UHFFFAOYSA-N

Description

General description

Sodium ethoxide (Sodium ethylate) is a sodium alkoxide. It has been synthesized by reacting sodium with ethanol. It undergoes decomposition in the presence of water to afford ethanol and sodium hydroxide. It is widely employed as a strong base in organic synthesis studies.

Sodium ethoxide is an alkoxide salt mainly used as a strong base in organic reactions such as deprotonation, dehydration and dehalogenation.

Application

Sodium ethoxide may be used for the preparation of tricarbonylchloro(glycinato)ruthenium(II) (CORM-3).[1]

Sodium ethoxide may be used as a base for the palladium catalyzed cross-coupling of aryl halides and alkenylboranes to synthesize arylated (E)-alkenes.

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H228,H251,H302,H314
• pcodes: P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1A
• supp_hazards: EUH014,EUH071
• Storage Class: 4.2 - Pyrophoric and self-heating hazardous materials
• flash_point_f: 86.0 °F - closed cup
• flash_point_c: 30 °C - closed cup