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Supelco

Thifensulfuron-methyl

PESTANAL®, analytical standard

Synonym(s):

Harmony

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About This Item

Empirical Formula (Hill Notation):
C12H13N5O6S2
CAS Number:
Molecular Weight:
387.39
Beilstein:
7448062
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COC(=O)c1sccc1S(=O)(=O)NC(=O)Nc2nc(C)nc(OC)n2

InChI

1S/C12H13N5O6S2/c1-6-13-10(16-12(14-6)23-3)15-11(19)17-25(20,21)7-4-5-24-8(7)9(18)22-2/h4-5H,1-3H3,(H2,13,14,15,16,17,19)

InChI key

AHTPATJNIAFOLR-UHFFFAOYSA-N

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General description

Thifensulfuron-methyl belongs to the class of sulfonylurea pesticides, generally employed for controlling many grasses and broadleaved weed species, affecting cultivation of crops such as corn, potatoes, tomatoes, citrus, vines and rice.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Thifensulfuron-methyl may be used as an analytical reference standard for the quantification of the analyte in environmental matrices using various chromatography techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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J J Stry et al.
Journal of AOAC International, 83(3), 651-659 (2000-06-27)
Size-exclusion chromatography (SEC) was coupled to reversed-phase liquid chromatography/mass spectrometry for the determination of thifensulfuron-methyl and tribenuron-methyl in cottonseed and cotton gin trash. The limit of quantitation was 20 parts per billion (ppb), and the limit of detection was 6
Determination of sulfonylurea degradation products in soil by liquid chromatography-ultraviolet detection followed by confirmatory liquid chromatography-tandem mass spectrometry
Bossi R, et al.
Journal of Chromatography A, 855(2), 575-582 (1999)
Hafid Belhadj-Tahar et al.
Acta pharmaceutica (Zagreb, Croatia), 53(2), 111-118 (2004-02-07)
In vitro toxic effects of sulfonylurea herbicides (thifensulfuron-methyl and metsulfuron-methyl) were evaluated according to a new protocol. Physiological conditions were reproduced in order to boost toxicovigilance. Sulfonylureas and their hydrolysis products were added to biological substrates such as urea, alanine
Shoil M Greenberg et al.
Pest management science, 60(9), 849-858 (2004-09-24)
In laboratory, greenhouse and field tests, we determined the effects of combining full rates of the defoliants tribufos and thidiazuron and the herbicide thifensulfuron-methyl with half rates of the insecticides lambda-cyhalothrin or azinphos-methyl, and the combination of tribufos and thidiazuron

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