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402885

p-Toluenesulfonic acid monohydrate

ACS reagent grade, ≥98.5%, solid

p-Toluenesulfonic acid monohydrate
1 of 1 reviewers received a sample product or took part in a promotion

Synonym(s):

4-Methylbenzenesulfonic acid monohydrate, 4-Toluenesulfonic acid monohydrate, PTSA monohydrate, TsOH monohydrate

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Size/SKUAvailabilityPrice
5 g
Please contact Customer Service for Availability
1 130,00 CZK
100 g
Please contact Customer Service for Availability
1 360,00 CZK
500 g
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3 790,00 CZK
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11 300,00 CZK

About This Item

Linear Formula:
CH3C6H4SO3H · H2O
CAS Number:
Molecular Weight:
190.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-180-0
MDL number:
Beilstein/REAXYS Number:
3568023
Assay:
≥98.5%
Concentration:
≥98.5%
Form:
solid
Grade:
ACS reagent

1 130,00 CZK


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Product Name

p-Toluenesulfonic acid monohydrate, ACS reagent, ≥98.5%

grade

ACS reagent

Quality Segment

vapor density

5.9 (vs air)

assay

≥98.5%

form

solid

concentration

≥98.5%

clarity of soln

passes test

impurities

9.5-11.5% water

ign. residue

≤0.1%

mp

103-106 °C (lit.)

solubility

H2O: 10g + 50 mL, clear, colorless

anion traces

sulfate (SO42-): ≤0.3%

cation traces

Fe: ≤0.01%, Na: ≤0.002%, heavy metals (as Pb): ≤0.001%

functional group

tosylate

SMILES string

[H]O[H].Cc1ccc(cc1)S(O)(=O)=O

InChI

1S/C7H8O3S.H2O/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);1H2

InChI key

KJIFKLIQANRMOU-UHFFFAOYSA-N

General description

p-Toluenesulfonic acid monohydrate, an oxonium salt, is an inexpensive and easy to handle organic catalyst used in organic synthesis. The study of its crystalline structure shows that it is monoclinic with P21/c space group. Its solubility in aqueous sulfuric acid solutions has been studied.

Application

p-Toluenesulfonic acid monohydrate (p-TsOH·H2O) may be used as a catalyst in the synthesis of the following:
  • Unsymmetrical benzils.
  • Highly substituted piperidines.
  • 1,3,5-Trisubstituted benzenes by trimerization of alkynes.
  • Triazoloquinazolinone and benzimidazoquinazolinone derivatives.
  • 1,3,5-Trisubstituted pyrazoles derivatives.[1]
  • Selenated ketene dithioacetals.

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1 of 1

This Item
27815T3592089866
concentration

≥98.5%

concentration

-

concentration

-

concentration

-

grade

ACS reagent

grade

-

grade

-

grade

analytical standard

assay

≥98.5%

assay

≥99% (calc. to H2O free subst.)

assay

≥98%

assay

95.0-105.0% (anhydrous basis, T)

Quality Level

300

Quality Level

200

Quality Level

200

Quality Level

100

form

solid

form

solid

form

solid

form

solid

solubility

H2O: 10g + 50 mL, clear, colorless

solubility

-

solubility

-

solubility

-


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signalword

Warning

pictograms

Exclamation mark

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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Reviews

Active Filters

  1. Tempe, AZ
    • Reviews 2
    • Votes 5
    5 out of 5 stars.

    pTsOH

    It was in good conditions and good size, it arrives early

    Helpful?