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8.22040

N,N-Dimethyl-p-toluidine

for synthesis

Synonym(s):

N,N-Dimethyl-p-toluidine, 4-Dimethylaminotoluene

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Size/SKUAvailabilityPrice
5 mL
Please contact Customer Service for Availability
CZK 689.00
250 mL
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CZK 1,760.00
1 L
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CZK 4,950.00

About This Item

Linear Formula:
4-(CH3)C6H4N(CH3)2
CAS Number:
Molecular Weight:
135.21
UNSPSC Code:
12352116
EC Index Number:
202-805-4
NACRES:
NA.22
MDL number:
Assay:
≥98.0% (GC)
Form:
oil

CZK 689.00


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vapor pressure

0.1 hPa ( 20 °C)

Quality Segment

assay

≥98.0% (GC)

form

oil

autoignition temp.

425 °C

potency

1650 mg/kg LD50, oral (Rat)

bp

215 °C/1013 hPa

mp

-15 °C

transition temp

flash point 76 °C

density

0.94 g/cm3 at 20 °C

storage temp.

2-30°C

SMILES string

N(C)(C)c1ccc(cc1)C

InChI

1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3

InChI key

GYVGXEWAOAAJEU-UHFFFAOYSA-N

Application



  • Zinc catalysed electrophilic C–H borylation of heteroarenes: This article explores a zinc-catalyzed process for borylation of heteroarenes using N,N-dimethyl-p-toluidine (Grundy et al., 2021).


  • C–H bond sulfonylation of anilines with the insertion of sulfur dioxide under metal-free conditions: Details a sulfonylation reaction involving N,N-dimethyl-p-toluidine under metal-free conditions (Zhou et al., 2018).



Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.935 - 0.937
Identity (IR): passes test

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This Item
8.0007773970D189006
assay

≥98.0% (GC)

assay

≥98.0% (HPLC)

assay

≥98.0% (HPLC)

assay

99%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

bp

215 °C/1013 hPa

bp

306-308 °C/1013 hPa

bp

-

bp

211 °C (lit.), 90-92 °C/10 mmHg (lit.)

density

0.94 g/cm3 at 20 °C

density

-

density

-

density

0.937 g/mL at 25 °C (lit.)

form

oil

form

solid

form

crystals

form

liquid

storage temp.

2-30°C

storage temp.

2-30°C

storage temp.

2-8°C

storage temp.

-


pictograms

Skull and crossbonesHealth hazard

signalword

Danger

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2

target_organs

Respiratory Tract,Blood

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials



Certificates of Analysis (COA)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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