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900714

Sigma-Aldrich

N-((S)-1-((S)-4-Benzyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

≥95%

Synonym(s):

Chiral MPAO ligand

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About This Item

Empirical Formula (Hill Notation):
C17H24N2O2
CAS Number:
2079094-19-0
Molecular Weight:
288.38
UNSPSC Code:
12161600

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

functional group

amide
phenyl

storage temp.

2-8°C

Application

Chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp3)-H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

Other Notes

Formation of α-chiral centers by asymmetric β-C(sp3)–H arylation, alkenylation, and alkynylation

Hazard Statements

H413

Precautionary Statements

P273 - P501

Hazard Classifications

Aquatic Chronic 4

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Yu program focuses on efficient C–H bond activation for drug synthesis, using simple starting materials.

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