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Key Documents

87652

Sigma-Aldrich

Tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium fluoride solution

~0.3 M in benzene

Synonym(s):

Phosphazenium fluoride P5-F

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About This Item

Empirical Formula (Hill Notation):
C24H72FN16P5
CAS Number:
Molecular Weight:
758.80
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:

form

solution

concentration

~0.3 M in benzene

SMILES string

[F-].CN(C)P(=N[P+](N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C24H72N16P5.FH/c1-29(2)42(30(3)4,31(5)6)25-41(26-43(32(7)8,33(9)10)34(11)12,27-44(35(13)14,36(15)16)37(17)18)28-45(38(19)20,39(21)22)40(23)24;/h1-24H3;1H/q+1;/p-1

InChI key

YZLHWBJVVXMBGF-UHFFFAOYSA-M

Other Notes

Extremely strong and lipophilic "naked" fluoride source which can be dried without decomposition

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 1A - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B - STOT RE 1

Target Organs

Blood

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

12.2 °F - closed cup

Flash Point(C)

-11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

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R. Schwesinger et al.
GIT, 897-897 (1992)
M. Wollenweber et al
Angewandte Chemie (International Edition in English), 106, 84-84 (1994)

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