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Sigma-Aldrich

Poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5-diyl)

Synonym(s):

POT-co-DOT

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About This Item

Linear Formula:
(C12H18S)m(C14H22OS)n
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

mol wt

Mn 8,000
Mw 21,000

fluorescence

λex 490 nm; λem 600 nm

Mw/Mn

2.5

General description

Poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5-diyl) (POT-co-DOT) is a regioregular conducting copolymer, which can be used as a donor material in electrochemical devices. It has a small band gap and forms an absorption spectrum in the red and infrared regions.
Typical Octyl thiophene:Decyloxythiophene = 1:1 (molar ratio). Synthesis, electrochemical and photophysical properties of poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5-diyl)s (POT-co-DOT) copolymer via condensation polymerization has been reported. Application of POT-Co-DOT to electrophoretic deposition has been reported in a separate study.

Application

Conducting polymer
POT-co-DOT can be used as a conjugating polymer for the fabrication of polymeric solar cells (PSCs) and bulk heterojunction based solar cells with power conversion efficiency (PCE).

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Regioregular copolymers of 3-alkoxythiophene and their photovoltaic application
Shi C, et al.
Journal of the American Chemical Society, 128(27), 8980-8986 (2006)
Kazuya Tada
The journal of physical chemistry. B, 117(6), 1628-1632 (2012-07-26)
Electrophoretic deposition is a useful and efficient technique to deposit conjugated polymers, if suitable suspension of the target polymer is obtained. Unfortunately, neither general theory nor universal procedure for the preparation of a suspension suitable for electrophoretic deposition has seemed
Effects of alkylthio and alkoxy side chains in polymer donor materials for organic solar cells
Cui C and Wong W
Macromolecular Rapid Communications, 37(4), 287-302 (2016)
Electrophoretic Deposition of the Thiophene-Based Copolymer and Its Composites with C60
Tada K
The Journal of Physical Chemistry B, 117(6), 1628-1632 (2012)
Chenjun Shi et al.
Journal of the American Chemical Society, 128(27), 8980-8986 (2006-07-06)
Low band gap conjugated polymers with proper energy levels for charge transfer are required to achieve high-efficiency polymer solar cells. We report the synthesis and characterization of two new regioregular copolymers that are based on 3-alkoxythiophene monomers: poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5-diyl) (POT-co-DOT) and

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