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668729

Sigma-Aldrich

Diethylzinc

packaged for use in deposition systems

Synonym(s):

DEZn, Et2Zn, DEZ, Zincdiethyl

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About This Item

Linear Formula:
(C2H5)2Zn
CAS Number:
557-20-0
Molecular Weight:
123.51
Beilstein:
3587207
EC Number:
209-161-3
MDL number:
MFCD00009021
UNSPSC Code:
12352103
PubChem Substance ID:
24885000
NACRES:
NA.23

form

liquid

refractive index

n20/D 1.498 (lit.)

bp

117 °C (lit.)

mp

−28 °C (lit.)

density

1.205 g/mL at 25 °C (lit.)

SMILES string

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChI key

HQWPLXHWEZZGKY-UHFFFAOYSA-N

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General description

Atomic number of base material: 30 Zinc

Application

Precursors Packaged for Depositions Systems
Reacted with water in a low temperature (<200°C) atomic layer deposition of polycrystalline ZnO layers displaying exciton photoluminescence at room temperature.

Signal Word

Danger

Hazard Statements

H250,H260,H314,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

Supplementary Hazards

EUH014

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of Applied Physics, 103, 033515-033515 (2008)
Takuji Hirose et al.
The Journal of organic chemistry, 76(13), 5413-5428 (2011-05-20)
Twenty chiral 1,3-amino sulfonamides of two classes (2a-i and 3a-k) have been prepared from (-)-cis-2-benzamidocyclohexanecarboxylic acid (1) and studied as ligands for catalytic enantioselective addition of Et(2)Zn to a variety of aromatic and aliphatic aldehydes. The ligands 2 and 3
Shaohua Gou et al.
Chirality, 23(2), 105-112 (2010-06-16)
New amino acid-based modular chiral ligands were readily synthesized and used to catalyze the asymmetric conjugate addition of Et(2) Zn to various cyclic enones in the presence of a variety of copper sources. Moderately high ee of up to 72%
Zhiyan Huang et al.
The Journal of organic chemistry, 72(4), 1373-1378 (2007-02-10)
A novel class of sulfinamido alcohol ligands 1-6 was synthesized from (S)-tert-butanesulfinamide. These ligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions of diethylzinc to aromatic aldehydes.
Weimin Lin et al.
The Journal of organic chemistry, 74(2), 645-651 (2008-12-06)
The application of a zinc carbenoid-mediated chain-extension reaction to a functionalized peptide isostere is reported. The cleavage site of human CVM protease was utilized as a target for testing the synthetic methodology. The utility of this chain-extension reaction is demonstrated
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