511609
Aluminum-tri-sec-butoxide
99.99% trace metals basis
Synonym(s):
Aluminum sec-butoxide
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About This Item
Linear Formula:
Al[OCH(CH3)C2H5]3
CAS Number:
Molecular Weight:
246.32
Beilstein:
3910908
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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Assay
99.99% trace metals basis
form
liquid
autoignition temp.
763 °F
expl. lim.
9.8 %
reaction suitability
core: aluminum
bp
200-206 °C/30 mmHg (lit.)
density
0.967 g/mL at 25 °C (lit.)
SMILES string
CCC(C)O[Al](OC(C)CC)OC(C)CC
InChI
1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
InChI key
WOZZOSDBXABUFO-UHFFFAOYSA-N
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Features and Benefits
Has been utilized in making high-surface-area alumina using 2,4-pentanedione (Aldrich product P775-4) as a chelating agent.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
78.8 °F - closed cup
Flash Point(C)
26 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Tantalum compounds as heterogeneous catalysts for saccharide dehydration to 5-hydroxymethylfurfural.
Fengli Yang et al.
Chemical communications (Cambridge, England), 47(15), 4469-4471 (2011-03-04)
A new solid acid, based on tantalum hydroxide, was used to catalyze saccharide dehydration into 5-hydroxymethylfurfural (HMF) with high catalytic activity and excellent stability in a water-2-butanol biphasic system. Furthermore, good results were also obtained from Jerusalem artichoke juice with
Flaminia Rondino et al.
Physical chemistry chemical physics : PCCP, 13(3), 818-824 (2010-12-07)
Diastereomeric adducts between (S)-1-(4-fluorophenyl)-ethanol and R and S 2-butanol, formed by supersonic expansion, have been investigated by means of a combination of mass selected resonant two-photon ionization-spectroscopy and infrared depletion spectroscopy. Chiral recognition is evidenced by the specific spectroscopic signatures
Saeko Shin et al.
The journal of physical chemistry. A, 110(6), 2122-2129 (2006-02-10)
The vibrational circular dichroism (VCD) spectra of (S)-(+)-2-butanol have been observed in dilute CS(2) solutions. Two strong VCD bands are assigned mainly to the OH bending modes with the aid of quantum chemical calculations. The calculated VCD spectra corresponding to
Feng Gao et al.
Journal of the American Chemical Society, 129(49), 15240-15249 (2007-11-16)
The enantioselective chemisorption of R- and S-propylene oxide has been measured either on clean Pd(111) that has been exposed to S-2-butanol at various temperatures to vary the proportion of 2-butanol and 2-butoxide species or by adsorbing S-2-butanol on oxygen-covered Pd(111)
Timothy E Morey et al.
AIDS and behavior, 17(1), 298-306 (2012-09-25)
A breath-based adherence system to document ingestion of oral medications (e.g., HAART) was investigated. Specifically, the food additive 2-butanol, which can be easily packaged with a drug, is converted via alcohol dehydrogenase to the volatile metabolite 2-butanone that rapidly appears
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