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Sigma-Aldrich

Ammonium trifluoroacetate

98%

Synonym(s):

Trifluoroacetic acid ammonium salt

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About This Item

Linear Formula:
CF3CO2NH4
CAS Number:
3336-58-1
Molecular Weight:
131.05
EC Number:
222-072-4
MDL number:
MFCD00012615
UNSPSC Code:
12352302
PubChem Substance ID:
24854342
NACRES:
NA.22

Quality Level

200

Assay

98%

form

crystals

mp

123-125 °C (lit.)

SMILES string

N.OC(=O)C(F)(F)F

InChI

1S/C2HF3O2.H3N/c3-2(4,5)1(6)7;/h(H,6,7);1H3

InChI key

YCNIBOIOWCTRCL-UHFFFAOYSA-N

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General description

Ammonium Trifluoroacetate is used as a catalyst in organic synthesis and as an additive in the mobile phase for chiral racemate separation.

Application

Used in the synthesis of hexafluoro-2-aminopentan-4-one ligand and in tuning and calibrating new liquid chromatography/mass spectrometry systems.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of Fluorine Chemistry, 27, 371-371 (1985)
Nimisha Thakur et al.
Chirality, 31(9), 688-699 (2019-07-19)
The enantiomeric excess of chiral starting materials is one of the important factors determining the enantiopurity of products in asymmetric synthesis. Fifty-one commercially available chiral reagents used as building blocks, catalysts, and auxiliaries in various enantioselective syntheses were assayed for
Ammonium Trifluoroacetate-Mediated Synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones
Chandran R et al.
International Scholarly Research Network, 2011 (2011)
Tejas Wattamwar et al.
European journal of mass spectrometry (Chichester, England), 26(2), 117-130 (2019-10-03)
A rapid and sensitive liquid chromatography-mass spectrometry method was developed, optimized, and validated for simultaneous quantification of empagliflozin and metformin in human plasma using empagliflozin D4and metformin D6 as an internal standard. Analytes and internal standard were extracted from plasma
Garrett Hellinghausen et al.
Journal of pharmaceutical and biomedical analysis, 155, 70-81 (2018-04-07)
Core-shell particles (superficially porous particles, SPPs) have been proven to provide high-throughput and effective separations of a variety of chiral molecules. However, due to their limited commercialization, many separations have not been reported with these stationary phases. In this study
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