192201
2,4,6-Trimethylbenzenesulfonohydrazide
97%
Synonym(s):
2-Mesitylenesulfonohydrazide
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About This Item
Linear Formula:
(CH3)3C6H2SO2NHNH2
CAS Number:
Molecular Weight:
214.28
Beilstein:
2118380
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
mp
112-114 °C (dec.) (lit.)
functional group
hydrazine
SMILES string
Cc1cc(C)c(c(C)c1)S(=O)(=O)NN
InChI
1S/C9H14N2O2S/c1-6-4-7(2)9(8(3)5-6)14(12,13)11-10/h4-5,11H,10H2,1-3H3
InChI key
JQUBKTQDNVZHIY-UHFFFAOYSA-N
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Application
2,4,6-Trimethylbenzenesulfonohydrazide has been used in the synthesis of:
- (E)-N′-(1-((1S*,4aR*,8aR*)-1-hydroxydecahydronaphthalen-4a-yl)ethylidene)-2,4,6-trimethylbenzenesulfonohydrazide
- complanadine alkaloids
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Concise Synthesis of 1, 4a-Bifunctionalised Decalin Building Blocks by CH Activation of Decalin.
Uosis-Martin M, et al.
Synlett, 2011(15), 2211-2213 (2011)
Mario Uosis-Martin et al.
The Journal of organic chemistry, 78(12), 6253-6263 (2013-05-30)
A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a model substrate accessed from unfunctionalized decalin. The key transformation affords
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