316385

Potassium fluoride on alumina

extent of labeling: 40 wt. % loading

• Lineární vzorec: KF
• Číslo CAS: 7789-23-3
• NACRES: NA.23
• PubChem Substance ID: 24859011
• UNSPSC Code: 12352302
• MDL number: MFCD00011398
• Form: solid

Vlastnosti

• form: solid
• Quality Segment: 100
• reaction suitability: core: potassium
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• extent of labeling: 40 wt. % loading
• greener alternative category: Aligned,
• SMILES string: [F-].[K+]
• InChI: 1S/FH.K/h1H;/q;+1/p-1
• InChI key: NROKBHXJSPEDAR-UHFFFAOYSA-M

Popis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Green etherification reagent of choice according to Glaxo-Smith-Kline's reagent guide.

Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6

Potassium fluoride loaded alumina can be used to catalyze:

• Dehydration of alkyl and aryl aldoximes into nitriles may be catalyze by potassium fluoride loaded on alumina.
• Palladium-catalysed reactions to prepare allylic thiol derivatives.
• N-Alkylation of carboxamides.

Bezpečnostní informace

• Piktogramy: GHS07
• Výstražné slovo: Warning
• Kódy nebezpečí: H302
• Bezpečnostní pokyny: P301 + P312 + P330
• Hazard Classifications: Acute Tox. 4 Oral
• Skladovací třída: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Co se děje?: WGK 3
• Bod vzplanutí (°F): Not applicable
• Bod vzplanutí (°C): Not applicable
• PPE (osobní ochranné prostředky): Eyeshields, Gloves, type N95 (US)