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283754

2(5H)-Furanone

98%

Synonyma:

γ-Crotonolactone, 2-Buten-1,4-olide

pro zobrazení organizačních a smluvních cen.

Vybrat velikost

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Vám/Skladová položkaDostupnostCena
1 g
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2 290,00 Kč
5 g
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8 990,00 Kč

O této položce

Empirický vzorec (Hillův zápis):
C4H4O2
Číslo CAS:
Molekulová hmotnost:
84.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-839-3
Beilstein/REAXYS Number:
383585
MDL number:
Assay:
98%
Form:
liquid

2 290,00 Kč


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Quality Segment

assay

98%

form

liquid

refractive index

n20/D 1.469 (lit.)

bp

86-87 °C/12 mmHg (lit.)

mp

4-5 °C (lit.)

density

1.185 g/mL at 25 °C (lit.)

functional group

ester

storage temp.

2-8°C

SMILES string

O=C1OCC=C1

InChI

1S/C4H4O2/c5-4-2-1-3-6-4/h1-2H,3H2

InChI key

VIHAEDVKXSOUAT-UHFFFAOYSA-N

General description

Chiral urea compounds catalyzed hetero-Michael addition reaction of 2(5H)-furanone (γ-crotonolactone) to pyrrolidine[1]. The quorum sensing inhibition activity by 2(5H)-furanone was studied using bioindicator strains[2].

Application

2(5H)-Furanone (γ-Crotonolactone) has been used in:
  • synthesis of (+)-L-733,060, (+)-CP-99,994 and (2S,3R)-3-hydroxypipecolic acid[3]
  • synthesis of 5-substituted 2(5H) furanones (γ-butenolides) via direct aldol reaction with aromatic aldehydes catalyzed by bifunctional aminothiourea and aminosquaramide organocatalysts[4]
  • Michael addition reactions for synthesis of lignans
  • three-component Michael-Aldol reactions with an aldehyde anda thiolate or carbanion

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

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Tato položka
360872479179468037
assay

98%

assay

99%

assay

97%

assay

95%

refractive index

n20/D 1.469 (lit.)

refractive index

-

refractive index

-

refractive index

n20/D 1.443 (lit.)

bp

86-87 °C/12 mmHg (lit.)

bp

105 °C/0.5 mmHg (lit.)

bp

-

bp

120-121 °C/18 mmHg (lit.)

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

density

1.185 g/mL at 25 °C (lit.)

density

-

density

-

density

1.08 g/mL at 25 °C (lit.)

form

liquid

form

-

form

-

form

-


Skladovací třída

10 - Combustible liquids

wgk

WGK 3

flash_point_f

213.8 °F - closed cup

flash_point_c

101 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Osvědčení o analýze (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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