CRM01345
Fluopyram
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
N-[2-[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]ethyl]-2-(trifluoromethyl)benzamide, N-{2-[3-Chloro-5-(trifluoromethyl)-2-pyridyl]ethyl}-α,α,α-trifluoro-o-toluamide
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About This Item
Empirical Formula (Hill Notation):
C16H11ClF6N2O
CAS Number:
Molecular Weight:
396.71
Beilstein:
11323270
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
Recommended Products
grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
form
solid
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
SMILES string
FC(F)(F)c1cnc(CCNC(=O)c2ccccc2C(F)(F)F)c(Cl)c1
InChI
1S/C16H11ClF6N2O/c17-12-7-9(15(18,19)20)8-25-13(12)5-6-24-14(26)10-3-1-2-4-11(10)16(21,22)23/h1-4,7-8H,5-6H2,(H,24,26)
InChI key
KVDJTXBXMWJJEF-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fluopyram belongs to the class of succinate dehydrogenase inhibitor (SDHI) fungicides that are also used as a nematicide. It binds to complex II and blocks the mitochondrial electron transport chain, a fundamental component of the Krebs cycle. It is used to control grey mold, white mold (sclerotinia), and powdery mildew in crops such as table grapes, pome fruit, stone fruits, and vegetables, in addition to being used as a seed treatment for the control of nematodes. It is a broad-spectrum systemic fungicide that is absorbed by plant roots and leaves and distributed throughout the plant.
Fluopyram was approved on 1st February 2014 under the Commission Implementing Regulation (EU) No 802/20133 as per Regulation (EC) No 1107/20094 as revised by the Commission Implementing Regulations (EU) No 540/20115 and 541/201. Maximum residue levels (MRLs) for fluopyram have been set according to Reg (EU) 2021/1807 in various products of plant and animal origin from 0.01 to 60 mg/kg. Fluopyram has to be monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fluopyram belongs to the class of succinate dehydrogenase inhibitor (SDHI) fungicides that are also used as a nematicide. It binds to complex II and blocks the mitochondrial electron transport chain, a fundamental component of the Krebs cycle. It is used to control grey mold, white mold (sclerotinia), and powdery mildew in crops such as table grapes, pome fruit, stone fruits, and vegetables, in addition to being used as a seed treatment for the control of nematodes. It is a broad-spectrum systemic fungicide that is absorbed by plant roots and leaves and distributed throughout the plant.
Fluopyram was approved on 1st February 2014 under the Commission Implementing Regulation (EU) No 802/20133 as per Regulation (EC) No 1107/20094 as revised by the Commission Implementing Regulations (EU) No 540/20115 and 541/201. Maximum residue levels (MRLs) for fluopyram have been set according to Reg (EU) 2021/1807 in various products of plant and animal origin from 0.01 to 60 mg/kg. Fluopyram has to be monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
Fluopyram CRM may also find its use as described below:
Fluopyram CRM may also find its use as described below:
- Method development for analyzing the succinate-dehydrogenase-inhibitor fungicide residue levels in vegetable and fruit samples by liquid chromatography-tandem mass spectrometry
- Development and validation of monoclonal antibody-based immunoassays to analyze fluopyram residues in food samples
- Simultaneous estimation of fluopyram and tebuconazole in watermelon and soil samples using QuEChERS and GC-MS based method
- Determination of fluopyram, flupyradifurone, and indaziflam in date fruit, pistachio, and soil samples by ultra-high performance liquid chromatography with tandem mass spectrometry(UHPLC-MS)
- Develop and validate a method based on QuEChERS and UHPLC-Orbitrap-MS to determine fluopyram and its metabolites in cherry tomato and cucumber
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Marta Vargas-Pérez et al.
Journal of the science of food and agriculture, 100(13), 4826-4833 (2020-06-06)
Fluopyram is a pesticide widely used in tomato and cucumber crops cultivation to control fungal diseases that develop especially in environments with moderate temperatures and high humidity, such as in a greenhouse. The pathway of fluopyram dissipation has been monitored
Dissipation and residue determination of fluopyram and tebuconazole residues in watermelon and soil by GC-MS
Dong B and Hu J
International Journal of Environmental Analytical Chemistry, 493-505 null
Antonio Abad-Fuentes et al.
Analytical and bioanalytical chemistry, 407(14), 4207-4211 (2015-03-23)
In recent years, a second generation of succinate-dehydrogenase-inhibitor (SDHI) fungicides has been introduced into the market for effective treatment of fruit and vegetable crops, with fluxapyroxad, boscalid, fluopyram, penflufen, bixafen, penthiopyrad, and isopyrazam being some of the members of this
Analysis of Alternative New Pesticide (Fluopyram, Flupyradifurone, and Indaziflam) Residues in Pistachio, Date, and Soil by Liquid Chromatography Triple Quadrupole Tandem Mass Spectrometry
Mahdavi V, et al.
Soil & Sediment Contamination, 373-383 null
Eric Ceballos-Alcantarilla et al.
Food chemistry, 288, 117-126 (2019-03-25)
Monoclonal antibody-based techniques have become a useful analytical technology in the agro-food sector. Nowadays, residues of the recently registered fungicide fluopyram are increasingly being found in quality control programs. In the present study, novel chemical derivatives of this pesticide were
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