Skip to Content
Merck
All Photos(6)

Key Documents

View All Documentation

248614

Sigma-Aldrich

Ammonium persulfate

ACS reagent, ≥98.0%

Synonym(s):

AP, APS, Ammonium peroxodisulfate, Ammonium peroxydisulfate, PER

Sign Into View Organizational & Contract Pricing
All Photos(6)

About This Item

Linear Formula:
(NH4)2S2O8
CAS Number:
7727-54-0
Molecular Weight:
228.20
EC Number:
231-786-5
MDL number:
MFCD00003390
UNSPSC Code:
12352300
PubChem Substance ID:
329752751
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

vapor density

7.9 (vs air)

Assay

≥98.0%

form

chunks or granules
powder or crystals

reaction suitability

reagent type: oxidant

impurities

≤0.005% insolubles
≤0.04 meq/g Titr. acid

ign. residue

≤0.05%

pH

1-2 (25 °C, 228 g/L)

anion traces

Cl- and ClO4-: ≤0.001%

cation traces

Fe: ≤0.001%
Mn: ≤0.5 ppm
heavy metals (as Pb): ≤0.005%

SMILES string

N.N.OS(=O)(=O)OOS(O)(=O)=O

InChI

1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)

InChI key

ROOXNKNUYICQNP-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Ammonium persulfateis a readily available oxidizing agent for various chemicaltransformations, and it is also usedas a bleaching agent in the chemical industry.

Application

Ammonium persulfate can be used as an oxidizing reagent for the solvent-free oxidation of:
  • Primary and secondary alcohols to corresponding carbonyl compounds in an aqueous medium.
  • Thiols to disulfides.
It can also be used as an initiator to initiate copolymerization of acrylonitrile and itaconic acid.
Catalyst for acrylamide gel polymerization.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

Aniline ACS reagent, ≥99.5%

Sigma-Aldrich

242284

Aniline

William H Thiel et al.
Methods in molecular biology (Clifton, N.J.), 1218, 187-199 (2014-10-17)
After a decade of work to address cellular uptake, the principal obstacle to RNAi-based therapeutics, there is now well-deserved, renewed optimism about RNAi-based drugs. Phase I and II studies have shown safe, strong, and durable-gene knockdown (80-90%, lasting for a
Electrical conductivity response of polypyrrole to acetone vapor: effect of dopant anions and interaction mechanisms.
Ruangchuay L, et al.
Synthetic Metals, 140(1), 15-21 (2004)
Solid state deoximation with ammonium persulfate-silica gel: Regeneration of carbonyl compounds using microwaves.
Varma RS and Meshram HM.
Tetrahedron Letters, 38(31), 5427-5428 (1997)
J M Brewer
Science (New York, N.Y.), 156(3772), 256-257 (1967-04-14)
Ammonium persulfate, a common polymerizing agent for acrylamide gels, can inactivate yeast enolase and produce increased electrophoretic heterogeneity during disc electrophoresis in gels containing 8M urea. The use of riboflavin and light for polymerization or thioglycolate for removal of the
T Simonsson et al.
Nucleic acids research, 26(5), 1167-1172 (1998-04-04)
The c-myc oncogene is one of the most commonly malfunctioning genes in human cancers, and is an attractive target for anti-gene therapy. Although synthetic oligonucleotides designed to silence c-myc expression via one of its major control elements function well in
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service