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932248

Sigma-Aldrich

Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}]

Synonym(s):

PFOPV

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About This Item

Linear Formula:
(C48H66O2)n
CAS Number:
475101-36-1
UNSPSC Code:
12352207
NACRES:
NA.23

description

UV: 480 nm (in THF)

PL: 539 nm (in THF)

Eg = 2.3 eV

Quality Level

100

mol wt

Mw ≥20,000 Da by GPC

energy gap

2.3 eV (Eg (HOMO-LUMO gap))

solubility

THF: soluble
chloroform: soluble (or chlorobenzene)
toluene: soluble

λmax

480 nm±5 nm in THF

fluorescence

λem 508 nm±10 nm in THF
λem 539 nm±10 nm in THF

Orbital energy

HOMO 4.4 eV 
LUMO 2.1 eV 

Application

Polymer Emitting Layers for Solution-Processed OLEDs; green emission.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Lasing and Transport Properties of Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-co-(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene)] (POFP) for the Application of Diode-Pumped Organic Solid Lasers
Tang Z, et al.
Nanoscale Research Letters, 12(1), 602-602 (2017)

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