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909181

Sigma-Aldrich

2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):
C25H26BF4N
CAS Number:
1621019-97-3
Molecular Weight:
427.29
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

Related Categories

Application

Robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

The direct anti-Markovnikov addition of mineral acids to styrenes

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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901368

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Dale J Wilger et al.
Nature chemistry, 6(8), 720-726 (2014-07-24)
The direct anti-Markovnikov addition of strong Brønsted acids to alkenes remains an unsolved problem in synthetic chemistry. Here, we report an efficient organic photoredox catalyst system for the addition of HCl, HF and also phosphoric and sulfonic acids to alkenes

Related Content

Nicewicz Group – Professor Product Portal

The Nicewicz lab is focused on the discovery of new and powerful reaction methodologies that proceed via the intermediacy of highly reactive cation radical species. Included in these transformations are anti-Markovnikov selective additions of amines, alcohols, carboxylic acids, amides and mineral acids to alkenes.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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