87189
1-Tetradecene
≥97.0% (GC)
Synonym(s):
1-Butadecene, n-Tetradec-1-ene, alpha-Tetradecene
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About This Item
Linear Formula:
CH3(CH2)11CH=CH2
CAS Number:
Molecular Weight:
196.37
Beilstein:
1701156
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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vapor density
6.8 (vs air)
Assay
≥97.0% (GC)
form
liquid
autoignition temp.
455 °F
refractive index
n20/D 1.436 (lit.)
n20/D 1.436
bp
251 °C (lit.)
mp
−13-−11 °C (lit.)
density
0.775 g/mL at 25 °C (lit.)
functional group
allyl
SMILES string
CCCCCCCCCCCCC=C
InChI
1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChI key
HFDVRLIODXPAHB-UHFFFAOYSA-N
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Application
1-Tetradecene can be used as a reactant to synthesize:
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
- 2-Tetradecanone via PdCl2/CrO3 catalyzed oxidation reaction.
- (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.
It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1
Supplementary Hazards
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F
Flash Point(C)
110 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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