767654
cis-Dichlorobis(dimethyl sulfoxide)platinum(II)
97%
Synonym(s):
cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)2Cl2
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About This Item
Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS Number:
Molecular Weight:
422.25
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
reaction suitability
core: platinum
reagent type: catalyst
mp
218-224 °C
SMILES string
Cl[Pt]Cl.CS(C)=O.CS(C)=O
InChI
1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2
InChI key
KDADQDWVKZJTDQ-UHFFFAOYSA-L
Related Categories
General description
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst.
Application
cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:
- Catalyst in the oleum-mediated (SO3-H2SO4) methane oxidation to form methyl bisulfate (MBS).
- Precursor in the synthesis of cyclometalated complexes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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R Gorodetsky et al.
Medical physics, 20(4), 1007-1012 (1993-07-01)
Noninvasive analysis of heavy elements in external tissues by diagnostic-x-ray spectrometry (DXS) is presented. Pt can be detected accurately with sensitivity below 1 microgram/g wet weight of tissue. In the present paper the possibility to monitor Pt accumulation and clearance
K R Grigorian et al.
Biofizika, 56(1), 31-34 (2011-03-30)
The interaction of cis-[PtCl2(Me2SO)2] with human serum albumin (HSA) and the sensitivity of the complex towards the thermal denaturation depending on the duration of incubation have been studied by absorption and fluorescence spectroscopy methods. Optimum conditions for cis-[PtCl2(Me2SO)2] binding to
B A Teicher et al.
Cancer chemotherapy and pharmacology, 32(4), 315-319 (1993-01-01)
The survival of bone-marrow granulocyte-macrophage colony-forming units (CFU-GM), an alkylating-agent-sensitive normal tissue, was assessed in mice bearing the EMT-6 parental tumor or the in vivo resistant EMT-6/CDDP, EMT-6/CTX, EMT-6/Thio, and EMT-6/Carbo tumors. The survival pattern of the bone-marrow CFU-GM recapitulated
K Nishio et al.
International journal of cancer, 55(4), 616-622 (1993-10-21)
cis-Diamminedichloroplatinum(II) (CDDP) induced G2-phase arrest in PC-9 human cancer cells. To elucidate how CDDP acts on cell-cycle regulation, we analyzed the effect of CDDP on cell-cycle regulators such as p34cdc2 protein kinase. p34cdc2 protein kinase activity was maximum in G2
Treatment of pathological stage T3N+M0 bladder cancer: the case for observation.
D A Corral et al.
Seminars in urology, 11(2), 64-68 (1993-05-01)
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