634565

Lithium perchlorate

battery grade, dry, 99.99% trace metals basis

• Synonym(s): Lithium cloricum, Perchloric acid, lithium salt
• Linear Formula: LiClO₄
• CAS Number: 7791-03-9
• Molecular Weight: 106.39
• EC Number: 232-237-2
• MDL number: MFCD00011079
• UNSPSC Code: 26111700
• PubChem Substance ID: 24882632
• NACRES: NA.23
• Assay: 99.99% trace metals basis
• form: powder and chunks
• solubility: H₂O: 106.4 g/L at 20 °C

Properties

• Quality Level: 200
• Assay: 99.99% trace metals basis
• form: powder and chunks
• reaction suitability: reagent type: oxidant
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 236 °C (lit.)
• solubility: H₂O: 106.4 g/L at 20 °C
• application(s): battery manufacturing
• greener alternative category: Enabling,
• SMILES string: [Li+].[O-]Cl(=O)(=O)=O
• InChI: 1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI key: MHCFAGZWMAWTNR-UHFFFAOYSA-M

Description

General description

Lithium perchlorate (LiClO₄) is a neutral salt with high solubility. LiClO₄ finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.[1]

Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[2][3][4][5]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiClO₄ can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.[6][7]

LiClO₄ is used as an electrolyte salt for lithium-sulfur batteries.[1] LiClO₄ acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.[8]

Safety Information

• Pictograms: GHS03,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H272,H302,H314,H335
• Precautionary Statements: P210 - P260 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves