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About This Item
Empirical Formula (Hill Notation):
C9H20O2Si
CAS Number:
Molecular Weight:
188.34
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
refractive index
n20/D 1.531 (lit.)
bp
195-197 °C (lit.)
density
0.901 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)[Si](C)(C)OCC1CO1
InChI
1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3
InChI key
YANSSVVGZPNSKD-UHFFFAOYSA-N
General description
tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water.
Application
tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
158.0 °F - closed cup
Flash Point(C)
70 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of Glycidol-and Sugar-Derived Bicyclic ?-and ?/d-Amino Acids for Peptidomimetic Design.
Danieli E, et al.
European Journal of Organic Chemistry, 2005(20), 4372-4381 (2005)
Practical access to highly enantioenriched C-3 building blocks via hydrolytic kinetic resolution.
Furrow ME, et al.
The Journal of Organic Chemistry, 63(20), 6776-6777 (1998)
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