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Key Documents

52586

Sigma-Aldrich

1,1,1,3,3,3-Hexakis(dimethylamino)diphosphazenium tetrafluoroborate

≥98.0% (T)

Synonym(s):

Bis[tris(dimethylamino)phosphoranylidene]ammonium tetrafluoroborate, Phosphazenium tetrafluoroborate P2-BF4

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About This Item

Linear Formula:
[[(CH3)2N]3P=]2N(BF4)
CAS Number:
Molecular Weight:
427.21
Beilstein:
5470923
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

Assay

≥98.0% (T)

form

solid

mp

≥260 °C (lit.)

functional group

amine

SMILES string

F[B-](F)(F)F.CN(C)P(=[N+]=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C12H36N7P2.BF4/c1-14(2)20(15(3)4,16(5)6)13-21(17(7)8,18(9)10)19(11)12;2-1(3,4)5/h1-12H3;/q+1;-1

InChI key

DPIDWCQJGWFENO-UHFFFAOYSA-N

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Other Notes

Phase transfer catalyst directing enolate alkylation towards O-substitution; Starting material for preparing the corresponding fluoride, an extremely reactive naked fluoride, with KF

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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R. Schwesinger et al
Angewandte Chemie (International Edition in English), 103, 1376-1376 (1991)
E.V. Dehmlow et al.
Chemische Berichte, 126, 2765-2765 (1993)

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