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448753

Sigma-Aldrich

4,4′-Bis(chloromethyl)-1,1′-biphenyl

95%

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About This Item

Linear Formula:
ClCH2C6H4C6H4CH2Cl
CAS Number:
1667-10-3
Molecular Weight:
251.15
EC Number:
216-784-4
MDL number:
MFCD00674019
UNSPSC Code:
12352100
PubChem Substance ID:
24868429
NACRES:
NA.22

Assay

95%

form

solid

mp

126 °C (dec.) (lit.)

functional group

chloro

SMILES string

ClCc1ccc(cc1)-c2ccc(CCl)cc2

InChI

1S/C14H12Cl2/c15-9-11-1-5-13(6-2-11)14-7-3-12(10-16)4-8-14/h1-8H,9-10H2

InChI key

INZDTEICWPZYJM-UHFFFAOYSA-N

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW1732
MKCM4264
MKBW9451V
MKBR8532V
MKBN3227V

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Chang-Tao Hsiao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(4), 1358-1364 (2011-01-19)
Pyrolytic carbon thin films were deposited on quartz plates through a chemical vapor deposition process, by using a biphenyl precursor, 4,4'-bis(chloromethyl-1,1'-biphenyl). The pyrolytic carbons were microporous and catalytic toward reduction of tri-iodide, and the films thus obtained possessed a metallic
Reaction of 4, 4'-bis (chloromethyl)-1, 1'-biphenyl and phenol in two-phase medium via phase-transfer catalysis.
Wang M-L and Lee Z-F.
J. Mol. Catal. A: Chem., 264(1), 119-127 (2007)
Lukas Rübenach et al.
ChemSusChem, 12(15), 3627-3634 (2019-05-10)
The utilization of biomass is one of the major challenges for the transition from fossil to renewable resources. Often, the separation of the desired product from the reaction mixture is the most energy-intensive step. Liquid-phase adsorption is a promising separation
Hung-Ming Yang et al.
Ultrasonics sonochemistry, 21(1), 395-400 (2013-08-27)
The catalytic esterification of sodium 4-hydroxybenzoate with benzyl bromide by ultrasound-assisted solid-liquid phase-transfer catalysis (U-SLPTC) was investigated using the novel dual-site phase-transfer catalyst 4,4'-bis(tributylammoniomethyl)-1,1'-biphenyl dichloride (BTBAMBC), which was synthesized from the reaction of 4,4'-bis(chloromethyl)-1,1'-biphenyl and tributylamine. Without catalyst and in

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