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Key Documents

441791

Sigma-Aldrich

Tris(2,4-di-tert-butylphenyl) phosphite

Synonym(s):

2,4-Bis(1,1-dimethylethyl)phenol phosphite (3:1), Tri(2,4-di-tert -butylphenyl) phosphite, Tri(2,4-di-t -butylphenyl) phosphite

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About This Item

Linear Formula:
[[(CH3)3C]2C6H3O]3P
CAS Number:
Molecular Weight:
646.92
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

mp

181-184 °C (lit.)

SMILES string

CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C

InChI

1S/C42H63O3P/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18/h19-27H,1-18H3

InChI key

JKIJEFPNVSHHEI-UHFFFAOYSA-N

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General description

Tris(2,4-di-tert-butylphenyl) phosphite is a triaryl based phosphite that can be used in catalysis and metallation. Its characteristic to undergo metallation reaction and provide a cost effective synthetic processes allows it to be useful in biaryl coupling reactions.

Application

It may be used as a chain extender and a processing stabilizer that facilitate the production of stable polymeric materials, which include polylactic acid (PLA), polyolefins, etc.

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction.
Albisson DA
Tetrahedron Letters, 39(52), 9793-9796 (1998)
Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions.
Albisson DA, et al.
Chemical Communications (Cambridge, England), 19, 2095-2096 (1998)
Study of the high temperature reactions of a hindered aryl phosphite (Hostanox PAR 24) used as a processing stabiliser in polyolefins.
Kriston I, et al.
Polymer Degradation and Stability, 95(9), 1883-1893 (2010)
Structure effect of phosphite on the chain extension in PLA.
Meng X, et al.
Polymer Degradation and Stability, 120(52), 283-289 (2015)
Maria F Poças et al.
Risk analysis : an official publication of the Society for Risk Analysis, 30(7), 1052-1061 (2010-04-23)
The use of probabilistic approaches in exposure assessments of contaminants migrating from food packages is of increasing interest but the lack of concentration or migration data is often referred as a limitation. Data accounting for the variability and uncertainty that

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