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406600

Sigma-Aldrich

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluoro-1,10-decanediol

97%

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About This Item

Linear Formula:
HOCH2(CF2)8CH2OH
CAS Number:
Molecular Weight:
462.13
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

solid

bp

132 °C/4 mmHg (lit.)

mp

135-137 °C (lit.)

functional group

fluoro
hydroxyl

SMILES string

OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CO

InChI

1S/C10H6F16O2/c11-3(12,1-27)5(15,16)7(19,20)9(23,24)10(25,26)8(21,22)6(17,18)4(13,14)2-28/h27-28H,1-2H2

InChI key

NSKCTPBWPZPFHW-UHFFFAOYSA-N

General description

2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluoro-1,10-decanediol (1H,1H,10H,10H-Perfluorodecane-1,10-diol) is a highly fluorinated decanediol. The molecular orientation and multilayer formation of 1H,1H,10H,10H-perfluorodecane-1,10-diol (FC10diol) at the hexane/water interface has been investigated. The interfacial tension of the hexane solution of 1H,1H,10H,10H-perfluorodecane-1,10-diol (FC10diol) against water has been measured. Its freezing point and density have been determined.

Application

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluoro-1,10-decanediol may be used in the preparation of diverse bromo(ester) (macro)initiators, required for the preparation of fluorinated pentablock as well as amphiphilic triblock copolymers with a central polyether segment.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Lact. - Repr. 1B - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization.
Jankova K and Hvilsted S.
Journal of Fluorine Chemistry, 126(2), 241-250 (2005)
Molecular orientation and miscibility of fluorinated α,ω-alkanediol and alcohol at the hexane/water interface.
Murakami D, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 354(1), 205-209 (2010)
Yaws CL.
The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals, 271-271 (2015)
Takanori Takiue et al.
The journal of physical chemistry. B, 113(44), 14667-14673 (2009-10-13)
The adsorption of 1H,1H,10H,10H-perfluorodecane-1,10-diol (FC10diol) at the hexane solution/water interface was investigated by the measurement of interfacial tension gamma as a function of pressure p and concentration m1 and the thermodynamic data analysis. The results obtained were compared with those

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