Skip to Content
Merck
All Photos(2)

Key Documents

395439

Sigma-Aldrich

Chloro(dimethyl)vinylsilane

97%

Synonym(s):

Dimethylvinylchlorosilane, Vinyldimethylchlorosilane

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
H2C=CHSi(CH3)2Cl
CAS Number:
Molecular Weight:
120.65
Beilstein:
1737688
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

liquid

refractive index

n20/D 1.414 (lit.)

bp

82-83 °C (lit.)

density

0.874 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(Cl)C=C

InChI

1S/C4H9ClSi/c1-4-6(2,3)5/h4H,1H2,2-3H3

InChI key

XSDCTSITJJJDPY-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilane, C4H9ClSi) is an organosilicon compound. It participates in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane. It undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts.

Application

Chloro(dimethyl)vinylsilane may be used in the synthesis of dimethyl(prop-2-ynyloxy)(vinyl)silane.
Chloro(dimethyl)vinylsilane may be used to prepare silicon-containing polymers, silaheterocycles, and new chelating ligands.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

23.0 °F - closed cup

Flash Point(C)

-5 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Vinylmetalloids: I. Coupling reactions of group IV metalloidal halides with magnesium in tetrahydrofuran.
Soderquist JA and Hassner A
Journal of Organometallic Chemistry, 156(1), 227-233 (1978)
Katritzky AR, et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond, 4, 611-611 (1995)
Schertzer BM.
The Development of Tandem Reactions Involving Enyne Metathesis to Form Substituted Cyclic Dienes, 209-209 (2006)
The Journal of Organic Chemistry, 57, 5279-5279 (1992)
Karolina Rachuta et al.
Physical chemistry chemical physics : PCCP, 21(36), 20384-20392 (2019-09-10)
In the course of studying silicon modifications to improve emission properties of commonly used organic compounds, biphenyl with dimethylsilylvinyl groups in the para position (3-Si) was investigated. A comparative study was performed on the exact C-analogue (3-C) and expanded to

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service