359327
N-Hexylmethylamine
96%
Synonym(s):
N-Methylhexylamine
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About This Item
Linear Formula:
CH3NH(CH2)5CH3
CAS Number:
Molecular Weight:
115.22
Beilstein:
1731685
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
96%
form
liquid
refractive index
n20/D 1.416 (lit.)
bp
140-142 °C (lit.)
density
0.76 g/mL at 25 °C (lit.)
SMILES string
CCCCCCNC
InChI
1S/C7H17N/c1-3-4-5-6-7-8-2/h8H,3-7H2,1-2H3
InChI key
XJINZNWPEQMMBV-UHFFFAOYSA-N
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General description
N-Hexylmethylamine is an acyclic secondary amine. Ruthenium-catalyzed reaction of N-hexylmethylamine with styrene has been reported. Transition metal-catalyzed intermolecular hydroamination of N-hexylmethylamine with 2-vinylnaphthalene has been reported.
Application
N-Hexylmethylamine may be used in the synthesis of dialkyldithiocarbamato cadmium complexes Cd[S2CNRR′]2.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
87.8 °F - closed cup
Flash Point(C)
31 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Masaru Utsunomiya et al.
Journal of the American Chemical Society, 126(9), 2702-2703 (2004-03-05)
A ruthenium-catalyzed intermolecular, anti-Markovnikov hydroamination of vinylarenes with secondary aliphatic and benzylic amines is reported. The combination of Ru(cod)(2-methylallyl)2, 1,5-bis(diphenylphosphino)pentane, and triflic acid was the most effective catalyst of those tested. Control reactions conducted without ligand or acid did not
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Journal of the American Chemical Society, 125(47), 14286-14287 (2003-11-20)
A transition metal-catalyzed intermolecular hydroamination of vinylarenes with alkylamines is reported. The combination of Pd(O2CCF3)4, DPPF, and TfOH was the most effective catalyst of those tested. Control experiments without palladium, acid, or ligand all occurred in low yield. The reaction
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