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338001

Sigma-Aldrich

Zirconium(IV) acetylacetonate

97%

Synonym(s):

2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate

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About This Item

Linear Formula:
Zr(C5H7O2)4
CAS Number:
Molecular Weight:
487.66
Beilstein:
4160373
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

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Assay

97%

form

powder

reaction suitability

core: zirconium
reagent type: catalyst

SMILES string

CC(=O)\C=C(\C)O[Zr](O\C(C)=C/C(C)=O)(O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/4C5H8O2.Zr/c4*1-4(6)3-5(2)7;/h4*3,6H,1-2H3;/q;;;;+4/p-4/b4*4-3-;

InChI key

FPFOSIXCIBGKOH-MTOQALJVSA-J

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This Item
GF11838809GF39839844GF03787746
assay

99%

assay

99%

assay

99%

assay

99.95%

manufacturer/tradename

Goodfellow 157-077-29

manufacturer/tradename

Goodfellow 118-388-09

manufacturer/tradename

Goodfellow 398-398-44

manufacturer/tradename

Goodfellow 037-877-46

mp

1453 °C (lit.)

mp

1453 °C (lit.)

mp

1453 °C (lit.)

mp

1453 °C (lit.)

resistivity

6.97 μΩ-cm, 20°C

resistivity

6.97 μΩ-cm, 20°C

resistivity

6.97 μΩ-cm, 20°C

resistivity

6.97 μΩ-cm, 20°C

bp

2732 °C (lit.)

bp

2732 °C (lit.)

bp

2732 °C (lit.)

bp

2732 °C (lit.)

General description

Zirconium(IV) acetylacetonate is a white crystalline organometallic solid widely used as a sol-gel precursor to synthesize Zirconium-based nanomaterials and thin films. It also finds application in the field of catalysis and polymer synthesis.

Application

Zirconium(IV) acetylacetonate can be used:
  • As a sol-gel precursor to synthesize zirconia nanoparticles with photocatalytic activity.[1]
  • As an additive to improve the performance of the electron transport layer in perovskite solar cells.[2]
  • To synthesize as-prepared zirconium acetylacetonate (a-ZrAcac) film as a cathode buffer layer in polymer solar cells. It exhibited an average power conversion efficiency (PCE) of 8.75% which is significantly improved than that of the devices with traditional Ca/Al cathode.[3]
  • To synthesize high-κ zirconium oxide gate dielectric for Organic Field-Effect Transistors at low voltage operation.[4]
  • To fabricate the conductive interlayers for quantum dot light-emitting devices(QLEDs), which enhances quantum efficiency, power efficiency, and longer operational lifetimes.[5]
  • As a ring-opening initiator to synthesize biodegradable polyacids.[6]
  • As a catalyst to synthesize polylactide terpolymers.[7]

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer
    Zhan'ao Tan, et al.
    Scientific Reports, 4, 4691-4691 (2014)
    Zirconium (IV) acetylacetonate: Ring-opening initiator mediating one-step synthesis of biodegradable polyacids
    Piotr Dobrzy'nski, et al.
    Advances in Polymer Technology, 2019-2019 (2019)
    Synthesis and properties of polylactide terpolymers P(LLA-TMC-GA) catalyzed by zirconium(IV)acetylacetonate
    Shaohua Wen, et al
    Applied Organometallic Chemistry, 32, e4177-e4177 (2018)
    Improving the TiO2 electron transport layer in perovskite solar cells using acetylacetonate-based additives
    Hsin-Hua Wang, et al.
    Journal of Materials Chemistry, 3, 9108-9115 (2015)
    Trzaska, S.T. et al.
    Chemistry of Materials, 11, 130-130 (1999)

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