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Assay
90%
form
liquid
refractive index
n20/D 1.443 (lit.)
bp
131 °C/17 mmHg (lit.)
density
0.849 g/mL at 25 °C (lit.)
functional group
allyl
SMILES string
C=CCCCCCCCCCCC=C
InChI
1S/C14H26/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-4H,1-2,5-14H2
InChI key
XMRSTLBCBDIKFI-UHFFFAOYSA-N
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General description
1,13-Tetradecadiene is an α-diolefin. Polymerization of 1,13-tetradecadiene using aluminum triisobutyl-titanium tetrachloride was reported.
Application
1,13-Tetradecadiene was grafted to hydrogenated B-doped silicon (100) surfaces. It was used in the synthesis of naturally occurring, biologically active pyridine alkaloids theonelladins C and D, niphatesine C and xestamine D.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
217.4 °F - closed cup
Flash Point(C)
103 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Monolayers of simple organic molecules on silicon studied by surface tools.
Surface and Interface Analysis : SIA, 34(1), 777-777 (2002)
Polymerization of Higher a-Diolefins with Metal Alkyl Coordination Catalysts1.
Journal of the American Chemical Society, 81(17), 4737-4744 (1959)
Synthesis of pyridine alkaloids via Pd-catalyzed coupling of 3-iodopyridine, 1, ?-dienes and nitrogen nucleophiles.
Tetrahedron Letters, 43(1), 21-23 (2002)
Polymers, 12(1) (2019-12-22)
Copolymerizations of 1-decene (DC) with 1,9-decadiene (DCD), 1-dodecene (DD) with 1,11-dodecadiene (DDD), and 1-tetradecene (TD) with 1,13-tetradecadiene (TDD), using Cp*TiMe2(O-2,6-iPr2C6H3) (1)-[Ph3C][B(C6F5)4] (borate) catalyst in the presence of AliBu3/Al(n-C8H17)3 proceeded in a quasi-living manner in n-hexane at -30 to -50 °C
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