278785
Triisobutylsilane
99%
Synonym(s):
Tris(2-methylpropyl)silane
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About This Item
Linear Formula:
[(CH3)2CHCH2]3SiH
CAS Number:
Molecular Weight:
200.44
Beilstein:
1738887
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
99%
refractive index
n20/D 1.435 (lit.)
bp
204-206 °C (lit.)
density
0.764 g/mL at 25 °C (lit.)
SMILES string
CC(C)C[SiH](CC(C)C)CC(C)C
InChI
1S/C12H28Si/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-13H,7-9H2,1-6H3
InChI key
BORQTRQJFUNMBC-UHFFFAOYSA-N
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General description
Triisobutylsilane (TIBS) is a versatile organosilicon compound that finds several applications in organic synthesis. Some of its common applications include desulfurization, deprotection of the N-boc group, and radical reactions.
Application
Triisobutylsilane can be used as a reagent in combination with trifluoroacetic acid (TFA) for the deprotection of the Fmoc functional group.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
228.2 °F - closed cup
Flash Point(C)
109 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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