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Key Documents

270032

Sigma-Aldrich

N,N′-Dimethylethylenediamine

85%

Synonym(s):

1,2-Bis(methylamino)ethane

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About This Item

Linear Formula:
CH3NHCH2CH2NHCH3
CAS Number:
Molecular Weight:
88.15
Beilstein:
878142
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

85%

form

liquid

refractive index

n20/D 1.431 (lit.)

bp

119 °C (lit.)

density

0.819 g/mL at 20 °C (lit.)

functional group

amine

SMILES string

CNCCNC

InChI

1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3

InChI key

KVKFRMCSXWQSNT-UHFFFAOYSA-N

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Application

N,N′-Dimethylethylenediamine was used to enhance CO2 adsorption. It was incorporated into H3[(Cu4Cl)3(BTTri)8 (CuBTTri; H3BTTri = 1,3,5-tri(1H-1,2,3-triazol-4-yl)benzene), a water-stable, triazolate-bridged framework, to form a metal–organic framework for CO2 separation.

Other Notes

remainder N-Methylethylenediamine

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

78.8 °F - closed cup

Flash Point(C)

26 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Enhanced carbon dioxide capture upon incorporation of N, N?-dimethylethylenediamine in the metal?organic framework CuBTTri.
McDonald TM, et al.
Chemical Science, 2(10), 2022-2028 (2011)
Xiaohu Deng et al.
The Journal of organic chemistry, 74(15), 5742-5745 (2009-06-17)
CuI/L5 (N,N'-dimethylethylenediamine) proves to be an efficient catalyst system for the amination of arylhalides with guanidines. The same catalyst system is then successfully applied to the one-step synthesis of 1-H-2-amino-benzimidazoles through tandem aminations of 1,2-dihaloarenes in modest yields. This methodology
Mohamed R Shehata et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 91, 383-388 (2012-03-06)
Pd(dmen)Cl(2) complex was synthesized and characterized, where dmen=N,N-dimethylethylenediamine. Stoichiometry and stability constants of the complexes formed between [Pd(dmen)(H(2)O)(2)](2+) and various biologically relevant ligands such as amino acids, peptides and dicarboxylic acids are investigated at 25 °C and at constant 0.1M
A Szent-Györgyi
Physiological chemistry and physics, 12(2), 99-110 (1980-01-01)
Most inanimate systems are build of closed-shell molecules in which electrons lack excitability and mobility. These electrons can be rendered reactive and mobile by taking out some of them, desaturating the system electronically. Single electrons can be taken out of
Benjamin J Rackstraw et al.
Biochimica et biophysica acta, 1576(3), 269-286 (2002-06-27)
PEGylated polyamidoamine (PAA) polymers were investigated for the production of sterically stabilised DNA delivery systems. Comparison of a PEGylated polymer (NG47) with a non-PEGylated polymer (NG49) showed similar binding of co-polymer to DNA by displacement of ethidium bromide (EB) and

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