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268607

Sigma-Aldrich

Formamidine hydrochloride

97%

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About This Item

Linear Formula:
HN=CHNH2 · HCl
CAS Number:
Molecular Weight:
80.52
Beilstein:
3906935
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

mp

84-87 °C (lit.)

functional group

amine

SMILES string

Cl[H].[H]C(N)=N

InChI

1S/CH4N2.ClH/c2-1-3;/h1H,(H3,2,3);1H

InChI key

NMVVJCLUYUWBSZ-UHFFFAOYSA-N

Application

Formamidine hydrochloride was used in the synthesis of imidazoleglycerol phosphate (IGP). It was also used in the synthesis of 5-methyl-4,6-dihydroxypyrimidine.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Reactions of oxidizing radicals with 4, 6-dihydroxypyrimidines as model compounds for uracil, thymine, and cytosine.
The Journal of Physical Chemistry, 91(2), 426-433 (1987)
Chung Hyeon Jang et al.
ACS nano, 14(10), 13246-13255 (2020-09-11)
A series of poly(fluorene-co-phenylene)-based anionic conjugated polyelectrolytes (CPEs) are prepared with varying sizes of counterions (tetramethylammonium, tetraethylammonium, and tetrabutylammonium (TBA+)) and studied as a hole-transporting layer (HTL) for sky-blue-emissive perovskite light-emitting diodes (PeLEDs). Ionic CPE HTLs improve the wettability, compatibility
The biosynthesis of histidine; D-erythro-imidazoleglycerol phosphate dehydrase.
B N AMES
The Journal of biological chemistry, 228(1), 131-143 (1957-09-01)
Federico Bertasi et al.
Physical chemistry chemical physics : PCCP, 19(38), 26230-26239 (2017-09-22)
This work describes the preparation of the new lipophilic ionic liquid tetraoctyl-formamidinium bis(trifluoromethanesulfonyl) imide (TOFATFSI), which is miscible with lower alkanes. In particular, this work focuses on the electric behaviour of TOFATFSI in the particularly challenging highly apolar environment of
Shulin Chen et al.
Organic letters, 13(23), 6152-6155 (2011-11-02)
A new N-sulfonyl formamidine synthesis was developed via NaI-catalyzed direct condensation of sulfonamide and formamide. The green methodology is featured by high atom economy, easily available starting materials, the lack of need for a transition-metal catalyst, no requirement of hazardous

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