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About This Item
Linear Formula:
(ClCF2CO)2O
CAS Number:
Molecular Weight:
242.94
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.347 (lit.)
bp
96-97 °C (lit.)
density
1.395 g/mL at 25 °C (lit.)
functional group
anhydride
SMILES string
FC(F)(Cl)C(=O)OC(=O)C(F)(F)Cl
InChI
1S/C4Cl2F4O3/c5-3(7,8)1(11)13-2(12)4(6,9)10
InChI key
VBJIFLOSOQGDRZ-UHFFFAOYSA-N
General description
Photolysis of the vapour of chlorodifluoroacetic anhydride has been studied over the range 19-201°C using 248nm radiation.
Application
Chlorodifluoroacetic anhydride has been used:
- for dual element acetylation tagging derivatization of amines by using microwave sustained helium emission detector
- as derivatization reagent in determination of estrone and 17β-estradiol in hair by GC-MS
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Photochemistry of anhydrides. Part 6.-Photolysis of chlorodifluoroacetic anhydride,(CF 2 ClCO) 2 O.
Watkins PE and Whittle E.
J. Chem. Soc., Faraday, 80(8), 2323-2329 (1984)
Multi-element taggant and dual homolog derivatization concepts in GC/MED.
Hagen DF, et al.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 40(1), 335-347 (1985)
M H Choi et al.
The Analyst, 125(4), 711-714 (2000-07-13)
An efficient procedure is described for the determination of estrone and 17 beta-estradiol in hair by gas chromatography-mass spectrometry (GC-MS). The method involves alkyloxycarbonylation with isobutyl chloroformate (isoBCF) of phenolic hydroxy groups after alkaline digestion of hair samples. The resulting
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