248592
Bismuth(III) nitrate pentahydrate
reagent grade, 98%
Synonym(s):
Bismuth trinitrate pentahydrate
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About This Item
Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
Molecular Weight:
485.07
EC Number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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grade
reagent grade
Quality Level
Assay
98%
form
crystals
reaction suitability
core: bismuth
reagent type: catalyst
bp
75-80 °C (lit.)
mp
30 °C (lit.)
SMILES string
O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
InChI
1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
InChI key
DPLOIMSBRDLLRI-UHFFFAOYSA-N
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General description
Bismuth(III) nitrate pentahydrate is the hydrated form of bismuth(III) nitrate. It is effectively used as a Lewis acid catalyst in organic synthesis for the conversion of thiocarbonyls to their carbonyl compounds; aromatic nitration; protection of carbonyl compounds; Michael reactions, and synthesis of coumarins.
Application
An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Ox. Sol. 2
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
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Polycyclic aromatic hydrocarbons are widespread in nature with a toxicity range from non-toxic to extremely toxic. A series of pyrenyl derivatives has been synthesized following a four-step strategy where the pyrene nucleus is attached with a basic heterocyclic moiety through
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