240532

Allyl alcohol

≥99%

• Synonym(s): 2-Propen-1-ol
• Linear Formula: CH₂=CHCH₂OH
• CAS Number: 107-18-6
• Molecular Weight: 58.08
• Beilstein: 605307
• EC Number: 203-470-7
• MDL number: MFCD00002920
• UNSPSC Code: 12352100
• PubChem Substance ID: 57648048
• NACRES: NA.22

Properties

• vapor density: 2 (vs air)
• Quality Level: 200
• vapor pressure: 23.8 mmHg ( 25 °C)
• Assay: ≥99%
• form: liquid
• autoignition temp.: 712 °F
• expl. lim.: 18 %
• refractive index: n20/D 1.412 (lit.)
• bp: 96-98 °C (lit.)
• mp: −129 °C (lit.)
• solubility: alcohol: miscible(lit.); chloroform: miscible(lit.); diethyl ether: miscible(lit.); water: miscible(lit.)
• density: 0.854 g/mL at 25 °C (lit.)
• functional group: hydroxyl
• SMILES string: OCC=C
• InChI: 1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
• InChI key: XXROGKLTLUQVRX-UHFFFAOYSA-N

Description

General description

Allyl alcohol is an industrially important olefinic alcohol. It is the raw material for the synthesis of a wide range of allylic derivatives such as allyl diglycol carbonate, allyl glycidyl ether, 1,4-butanediol, poly(styrene-allyl alcohol), etc. These derivatives find application as lens, coupling agents, plasticizers, crosslinking agents and coating additives. Allyl alcohol can be prepared by the rhenium catalyzed-deoxydehydration of glycerol.

The partial oxidation of allyl alcohol over oxygen-precovered gold surface was studied.

Application

Allyl alcohol may be used in the preparation of propylene via photocatalytic transfer hydrogenolysis in the presence of Pd/TiO₂ catalysts.

Allyl alcohol was used to grow fitter yeast (Saccharomyces cerevisiae).

Used to induce a mouse model of liver damage that has been used to study the mechanisms of hepatotoxicity and hepatic stem cell-mediated repair.

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H225,H301 + H331,H310,H315,H319,H335,H361fd,H410
• Precautionary Statements: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 71.6 °F - closed cup
• Flash Point(C): 22 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves