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Key Documents

236535

Sigma-Aldrich

Fluorosulfonic acid

purified by triple-distillation

Synonym(s):

Fluosulfuric acid

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About This Item

Linear Formula:
FSO3H
CAS Number:
Molecular Weight:
100.07
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

vapor density

3.5 (vs air)

Quality Level

vapor pressure

2.5 mmHg ( 25 °C)

purified by

triple-distillation

bp

165.5 °C (lit.)

mp

−87.3 °C (lit.)

density

1.726 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

OS(F)(=O)=O

InChI

1S/FHO3S/c1-5(2,3)4/h(H,2,3,4)

InChI key

UQSQSQZYBQSBJZ-UHFFFAOYSA-N

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Application

  • Polymerization of epoxidized triglycerides with fluorosulfonic acid: The article investigates the use of fluorosulfonic acid for the cationic polymerization of epoxidized triglycerides, exploring its potential in polymer chemistry (Biswas et al., 2016).

Packaging

Packaged in PFA/FEP bottles

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Skin Corr. 1A

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Y Takeuchi et al.
Chemical & pharmaceutical bulletin, 45(6), 1085-1088 (1997-06-01)
In order to develop novel methods for electrophilic and enantioselective fluorination of active methine compounds, preliminary experiments were carried out. The N-tosyl derivative 5 obtained from D-phenylglycine was fluorinated with FClO3 or diluted F2 gas to give the N-fluoro-N-tosyl derivative
Fumiaki Amano et al.
ChemSusChem, 12(9), 1925-1930 (2018-10-20)
Photoelectrochemical (PEC) water vapor splitting by using n-type semiconductor electrodes with a proton exchange membrane (PEM) enabled pure hydrogen production from humidity in ambient air. We proved a design concept that the gas-electrolyte-semiconductor triple-phase boundary on a nanostructured photoanode is
P A Seubert et al.
Archives of biochemistry and biophysics, 240(2), 509-523 (1985-08-01)
The kinetics of the forward ATP sulfurylase-catalyzed reaction were examined using a new assay based on 32PPi released from [gamma-32P]MgATP in the presence of inorganic sulfate. Replots yielded Vmaxf = 6.6 units mg protein-1, KmA = 0.13 mM, Kia =
Byungnam Kim et al.
Radiation research, 190(3), 309-321 (2018-06-19)
During the pulsed-electron beam direct grafting of neat styrene onto poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) substrate, the radiolytically-produced styryl and carbon-centered FEP radicals undergo various desired and undesired competing reactions. In this study, a high-dose rate is used to impede the undesired free
Roger L Snowden
Chemistry & biodiversity, 5(6), 958-969 (2008-07-12)
Using a novel, acid-mediated cyclization methodology, a direct access to Cetalox ((+/-)-1; a commercially important ambergris-type odorant) and various structurally related didehydro (i.e., 19, 26, and 30) and tetradehydro (i.e., 28 and 37/38) analogues is described. Treatment of either (E,E)-14

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