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221880

Sigma-Aldrich

Zirconium(IV) chloride

greener alternative

≥99.5% trace metals basis

Synonym(s):

Tetrachlorozirconium, Zirconium tetrachloride

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About This Item

Linear Formula:
ZrCl4
CAS Number:
10026-11-6
Molecular Weight:
233.04
EC Number:
233-058-2
MDL number:
MFCD00011306
UNSPSC Code:
12352302
PubChem Substance ID:
24852962
NACRES:
NA.23

vapor pressure

1 mmHg ( 190 °C)

Quality Level

200

Assay

≥99.5% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: zirconium

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤5000.0 ppm Trace Metal Analysis

transition temp

sublimation point 331 °C

density

2.8 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

, Aligned

SMILES string

Cl[Zr](Cl)(Cl)Cl

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4

InChI key

DUNKXUFBGCUVQW-UHFFFAOYSA-J

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct amide formation from unactivated carboxylic acids and amines

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H290,H314

Hazard Classifications

Met. Corr. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH071

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV5769
MKCV0740
MKCQ2342
MKCH0461
MKBS1405V

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Ines Sifaoui et al.
Frontiers in bioengineering and biotechnology, 9, 584115-584115 (2021-02-19)
In this study, the application of amphipods in vivo assays was evaluated. The main aim of this work was to check the potential use of this model in biocompatibility assessments of metal-organic frameworks (MOFs). Hence, six different MOFs were synthesized
Stefania Fioravanti et al.
Organic & biomolecular chemistry, 10(41), 8207-8210 (2012-09-26)
ZrCl(4) was found to be an ideal catalyst to promote aza-Henry reactions between trifluoromethyl aldimines and some nitro alkanes giving new fluorinated β-nitro amines. The reaction is strongly influenced by the CF(3) group, the yield by the alkyl chain of
Harish Kumar et al.
Ultrasonics sonochemistry, 15(2), 129-132 (2007-04-17)
Sonication of aromatic aldehydes, urea and ethyl acetoacetate in presence of solvent (ethyl alcohol) or solvent-less dry media (bentonite clay) supported-zirconium (IV) chloride (ZrCl(4)) as catalyst at 35 kHz gives 6-methyl-4-substitutedphenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid ethyl esters proficiently in high yields.
Ilanit Doron-Mor et al.
Langmuir : the ACS journal of surfaces and colloids, 20(24), 10727-10733 (2004-11-17)
Coordination self-assembly of bishydroxamate-based metal-organic multilayers on gold employing a layer-by-layer (LbL) approach was investigated. It is shown that the solution chemistry of the participating metal ion has a marked influence on the composition and properties of the multilayers. Use
Thomas A Dineen et al.
Journal of the American Chemical Society, 128(50), 16406-16409 (2006-12-15)
Two protocols for the transamidation of primary amides with primary and secondary amines, forming secondary and tertiary amides, respectively, are described. Both processes employ N,N-dialkylformamide dimethyl acetals for primary amide activation, producing N'-acyl-N,N-dialkylformamidines as intermediates, as widely documented in the
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