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183342

Sigma-Aldrich

Phenylselenyl chloride

98%

Synonym(s):

Benzeneselenenyl chloride, Benzeneselenyl chloride

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About This Item

Linear Formula:
C6H5SeCl
CAS Number:
Molecular Weight:
191.52
Beilstein:
1237091
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

solid

bp

120 °C/20 mmHg (lit.)

mp

59-62 °C (lit.)

SMILES string

Cl[Se]c1ccccc1

InChI

1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H

InChI key

WJCXADMLESSGRI-UHFFFAOYSA-N

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General description

Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.

Application

Phenylselenyl chloride was used in the synthesis of (cyclobut-1-enylselanyl)benzene.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Customers Also Viewed

Tetrahedron, 49, 1841-1841 (1993)
The Journal of Organic Chemistry, 58, 3355-3355 (1993)
Tetrahedron, 47, 4211-4211 (1991)
Le-Ping Liu et al.
The Journal of organic chemistry, 69(8), 2805-2808 (2004-04-13)
The reaction of methylenecyclopropanes 1 with phenylsulfenyl chloride or phenylselenyl chloride gives (cyclobut-1-enylsulfanyl)benzene or (cyclobut-1-enylselanyl)benzene along with ring-opened product in good total yields at 0 degrees C in various solvents. A plausible mechanism has been proposed.
Inorganic Chemistry, 30, 3402-3402 (1991)

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