168521
Luperox® DI, tert-Butyl peroxide
98%
Synonym(s):
tert-Butyl peroxide, Di-tert-butyl peroxide
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About This Item
Linear Formula:
(CH3)3COOC(CH3)3
CAS Number:
Molecular Weight:
146.23
Beilstein:
1735581
EC Number:
MDL number:
UNSPSC Code:
12352120
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor pressure
40 mmHg ( 20 °C)
Assay
98%
form
liquid
reaction suitability
reagent type: oxidant
refractive index
n20/D 1.3891 (lit.)
bp
109-110 °C (lit.)
density
0.796 g/mL at 25 °C (lit.)
functional group
peroxide
storage temp.
2-8°C
SMILES string
CC(C)(C)OOC(C)(C)C
InChI
1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3
InChI key
LSXWFXONGKSEMY-UHFFFAOYSA-N
Application
Luperox®DI, tert-Butyl peroxide has been used as a radical initiator to induce free radical polymerization. It has also been used as a cetane enhancer in a study to determine the phase behavior of carboxylate-based extended surfactant reverse micellar microemulsions with ethanol and vegetable oil/diesel blends.
Legal Information
Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Flam. Liq. 2 - Muta. 2 - Org. Perox. E
Storage Class Code
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 1
Flash Point(F)
42.8 °F - closed cup
Flash Point(C)
6 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Well-resolved ESR spectra of free pentadienyl radicals have been observed under photoirradiation of di-tert-butylperoxide (Bu(t)OOBu(t)) and polyunsaturated fatty acids in the absence of O(2), allowing us to determine the hfc values. The hfc values of linoleyl radical indicate that the
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Peroxyl radicals, as model for peroxyl radicals formed during autoxidation of lipids, have been generated in three solvent systems (cyclohexane, tetrahydrofuran and tert-butanol/water) by steady-state and laser flash photolysis, and their reaction with beta-carotene studied. Steady-state photolysis experiments showed that
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