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139335

Sigma-Aldrich

3-Methyl-1-(p-tolyl)triazene

98%

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About This Item

Linear Formula:
CH3C6H4N=NNHCH3
CAS Number:
Molecular Weight:
149.19
Beilstein:
1841442
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

mp

75-80 °C (lit.)

functional group

amine

SMILES string

CNN=Nc1ccc(C)cc1

InChI

1S/C8H11N3/c1-7-3-5-8(6-4-7)10-11-9-2/h3-6H,1-2H3,(H,9,10)

InChI key

DNGJVDGPCGXBFF-UHFFFAOYSA-N

Application

3-Methyl-1-(p-tolyl)triazene was used for methylation during simultaneous determination of hippuric and o-, m- and p-methylhippuric acids by gas chromatography.

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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J R Caperos et al.
British journal of industrial medicine, 34(3), 229-233 (1977-08-01)
A gas chromatographic method for simultaneous determination of hippuric and o-, m-, and p-methylhippuric acids (metabolites of toluene and xylene) in urine is described. The analytical procedure is based on the extraction of the aromatic metabolites with ethyl acetate containing
Yoshiaki Miura et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(17), 4797-4804 (2007-03-21)
A rapid and quantitative method for solid-phase methyl esterification of carboxy groups of various sialylated oligosaccharides has been established. The method employed a triazene derivative, 3-methyl-1-p-tolyltriazene, for facile derivatization of oligosaccharides immobilized onto general solid supports such as Affi-Gel Hz
Hidenori Takahashi et al.
Oncology reports, 44(6), 2757-2769 (2020-10-31)
The N‑glycoforms of glycoproteins modify protein function and control a number of biological pathways. The aim of the present study was to investigate the correlation between alterations in N‑glycans and cancer aggressiveness in terms of cancer cell invasion ability. The
Abrha G Gebrehiwot et al.
PloS one, 13(12), e0209515-e0209515 (2018-12-29)
Most glycomics studies have focused on understanding disease mechanisms and proposing serum markers for various diseases, yet the influence of ethnic variation on the identified glyco-biomarker remains poorly addressed. This study aimed to investigate the inter-ethnic serum N-glycan variation among
Motamed Elsayed Mahmoud et al.
Molecular biology reports, 46(3), 2733-2748 (2019-03-28)
Glycosylation is a post-translational protein modification in eukaryotes and plays an important role in controlling several diseases. N-glycan structure is emerging as a new paradigm for biomarker discovery of neuropsychiatric disorders. However, the relationship between N-glycosylation pattern and depression is

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