114693
1-Nitroso-2-naphthol
97%
Synonym(s):
1-Nitroso-2-hydroxynaphthalene
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About This Item
Linear Formula:
ONC10H6OH
CAS Number:
Molecular Weight:
173.17
Colour Index Number:
10005
Beilstein:
776947
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
mp
106-108 °C (dec.) (lit.)
functional group
C-nitroso
nitroso
SMILES string
Oc1ccc2ccccc2c1N=O
InChI
1S/C10H7NO2/c12-9-6-5-7-3-1-2-4-8(7)10(9)11-13/h1-6,12H
InChI key
YXAOOTNFFAQIPZ-UHFFFAOYSA-N
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Application
1-Nitroso-2-naphthol is the chelating ion-exchanger in the synthesis of alumina adsorbents that are of acidic, basic and neutral nature. It is used for the removal and preconcentration of Pb(II), Cu(II), Cr(III) from waste, as well as drinking water. It is also used in the preconcentration of cobalt using C(18) microcolumn with flow injection that is coupled to a flame atomic absorption spectrometry (FI-FAAS) system.
1-Nitroso-2-naphthol is used in the preparation of 1-nitroso-2-naphthol-sodium nitrite reagent.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cobalt determination with FI-FAAS after on-line sorbent preconcentration using 1-nitroso-2-naphthol.
Yingxue Ye et al.
Talanta, 57(5), 945-951 (2008-10-31)
The suitability of 1-nitroso-2-naphthol (NN) as a complexing agent for on-line preconcentration of cobalt using C(18) microcolumn with FI-FAAS system has been tested. Various parameters affecting the complex formation and its elution were optimized. Reagent solution (2.5x10(-3) mol l(-1)) and
Fluorometric measurement of tyrosine in serum and plasma.
J A Ambrose
Clinical chemistry, 20(4), 505-510 (1974-04-01)
C F Burrows et al.
Journal of the American Veterinary Medical Association, 183(3), 318-322 (1983-08-01)
The nitrosonapthol test, which qualitatively measures urinary excretion of 4-hydroxyphenylacetic acid and related compounds, was evaluated as a screening test for small intestinal disease in 60 dogs with chronic diarrhea. Test results were positive in 8 of 13 dogs with
N-acetyl-L-cysteine: an alternative to 2-mercaptoethanol in the reduction of Udenfriend's chromophore used for the determination of urinary 5-hydroxyindoleacetic acid.
M Zouheir Habbal
Clinica chimica acta; international journal of clinical chemistry, 130(2), 251-256 (1983-05-30)
Nayyef Aljaar et al.
The Journal of organic chemistry, 78(1), 154-166 (2012-11-28)
Reactions between 1-nitroso-2-naphthols and α-functionalized ketones such as α-bromo-, α-chloro-, α-mesyloxy-, α-tosyloxy-, and α-hydroxy ketones under basic conditions delivered 2-substituted naphtho[1,2-d][1,3]oxazoles in a single synthetic operation. The product formation was accompanied by the unexpected loss of the C═O group from
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