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47799

Supelco

Dibromomethane

analytical standard

Synonym(s):

Methylene bromide

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About This Item

Empirical Formula (Hill Notation):
CH2Br2
CAS Number:
Molecular Weight:
173.83
Beilstein:
969143
EC Number:
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:

grade

analytical standard

vapor density

6.05 (vs air)

vapor pressure

34.9 mmHg ( 20 °C)

CofA

current certificate can be downloaded

packaging

ampule of 1000 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.541 (lit.)

bp

96-98 °C (lit.)

mp

−52 °C (lit.)

density

2.477 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

storage temp.

2-30°C

SMILES string

BrCBr

InChI

1S/CH2Br2/c2-1-3/h1H2

InChI key

FJBFPHVGVWTDIP-UHFFFAOYSA-N

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Application

Dibromomethane may be used as an analytical reference standard for the quantification of the analyte in environmental samples and organic compounds using chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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A simple and sensitive method for the determination of volatile halogenated organic compounds in sea water in the amol l? 1 to pmol l? 1 range
Ekdahl A and Abrahamsson K
Analytica Chimica Acta, 357(3), 197-209 (1997)
Determination of non-metals in organic compounds by gas chromatography with a miniature capacitively coupled plasma emission detector
Guchardi R and Hauser.CP
Journal of Analytical Atomic Spectrometry, 19(8), 945-949 (2004)
Marcin Podsiadło et al.
Acta crystallographica. Section B, Structural science, 62(Pt 6), 1090-1098 (2006-11-17)
Dibromomethane, CH2Br2, and diiodomethane, CH2I2, have been in situ pressure-crystallized in a diamond-anvil cell and their structures determined by single-crystal X-ray diffraction at 0.61 and 0.16 GPa, respectively. The pressure-frozen CH2Br2 crystal is isostructural with its C2/c phase obtained by
D A Whittington et al.
Biochemistry, 40(12), 3476-3482 (2001-04-12)
To investigate the role of protein cavities in facilitating movement of the substrates, methane and dioxygen, in the soluble methane monooxygenase hydroxylase (MMOH), we determined the X-ray structures of MMOH from Methylococcus capsulatus (Bath) cocrystallized with dibromomethane or iodoethane, or
Glenn A Marsch et al.
Chemical research in toxicology, 17(1), 45-54 (2004-01-20)
The dihalomethane CH(2)Cl(2) is an industrial solvent of potential concern to humans because of its potential genotoxicity and carcinogenicity. To characterize DNA damage by dihalomethanes, a rapid DNA digestion under acidic conditions was developed to identify alkali labile DNA-dihalomethane nucleoside

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