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415146

Sigma-Aldrich

Triisopropyl orthoformate

97%

Synonym(s):

2,2′,2′′-[Methylidynetris(oxy)]tris[propane], 2-[Bis(propan-2-yloxy)methoxy]propane, 2-[Di(propan-2-yloxy)methoxy]propane, Tri(2-propyl) orthoformate, Tri(prop-2-yl) orthoformate, Tri-iso-propyl orthoformate, Triisopropyl orthoformate

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About This Item

Linear Formula:
CH[OCH(CH3)2]3
CAS Number:
Molecular Weight:
190.28
Beilstein:
1700668
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

liquid

refractive index

n20/D 1.397 (lit.)

bp

65-66 °C/18 mmHg (lit.)

density

0.854 g/mL at 25 °C (lit.)

SMILES string

CC(C)OC(OC(C)C)OC(C)C

InChI

1S/C10H22O3/c1-7(2)11-10(12-8(3)4)13-9(5)6/h7-10H,1-6H3

InChI key

FPIVAWNGRDHRSQ-UHFFFAOYSA-N

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General description

Triisopropyl orthoformate (TIPO) is formed during the reaction of dichlorofluoromethane with potassium isopropoxide in isopropyl alcohol. Separation of TIPO from n-hexane by dense carbon nanotube (CNT) membranes by pervaporation has been reported.

Application

Triisopropyl orthoformate may be used for the preparation of 2-(diisopropoxymethyl)oxirane.

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

107.6 °F - closed cup

Flash Point(C)

42 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Enzymatic Transformations 62. Preparative Scale Synthesis of Enantiopure Glycidyl Acetals using an Aspergillus niger Epoxide Hydrolase-Catalysed Kinetic Resolution.
Doumeche B, et al.
Advanced Synthesis & Catalysis, 348(14), 1948-1957 (2006)
Miao Yu et al.
Nano letters, 9(1), 225-229 (2008-12-23)
A method is presented to prepare high-density, vertically aligned carbon nanotube (VA-CNT) membranes. The CNT arrays were prepared by chemical vapor deposition (CVD), and the arrays were collapsed into dense membranes by capillary-forces due to solvent evaporation. The average space
Methylene Derivatives as Intermediates in Polar Reactions. XIX. The Reaction of Potassium Isopropoxide with Chloroform, Bromoform and Dichlorofluoromethane1.
Hine J, et al.
Journal of the American Chemical Society, 82(6), 1398-1401 (1960)

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