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Merck

Concerted proton motion in hydrogen-bonded trimers: a spontaneous Raman scattering perspective.

Physical chemistry chemical physics : PCCP (2006-06-16)
Philipp Zielke, Martin A Suhm
RESUMEN

Raman active symmetric O-H stretching modes are detected and assigned for the first time in isolated methanol, ethanol and methyl lactate trimers, providing insights into cluster structure, vibrational assignments and hydrogen-bond mediated couplings.

MATERIALES
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Sigma-Aldrich
(−)-Methyl L-lactate, 98%, optical purity ee: 97% (GLC)
Sigma-Aldrich
(+)-Methyl D-lactate, 98%, optical purity ee: 96% (GLC)
Sigma-Aldrich
Methyl DL-lactate, ≥97.0% (GC)