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179922

Sigma-Aldrich

Potassium phthalate monobasic

ACS reagent, acidimetric standard

Sinónimos:

KHP, Phthalic acid monopotassium salt, Potassium biphthalate, Potassium hydrogen phthalate

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About This Item

Fórmula lineal:
HOOCC6H4COOK
Número de CAS:
877-24-7
Peso molecular:
204.22
Beilstein/REAXYS Number:
3637128
EC Number:
212-889-4
MDL number:
MFCD00013070
UNSPSC Code:
12352100
PubChem Substance ID:
24850834
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

assay

99.95-100.05% dry basis

form

crystals

quality

acidimetric standard

impurities

≤0.002% S compounds
≤0.003% Cl compounds
≤0.005% insolubles

pH

4.00-4.02 (25.0 °C±0.2 °C, 0.05 M)

mp

295-300 °C (dec.) (lit.)

cation traces

Fe: ≤5 ppm
Na: ≤0.005%
heavy metals: ≤5 ppm (by ICP)

functional group

carboxylic acid

SMILES string

[K+].OC(=O)c1ccccc1C([O-])=O

InChI

1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1

InChI key

IWZKICVEHNUQTL-UHFFFAOYSA-M

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Application

Potassium phthalate monobasic may be used as a primary standard in acidimetric titration and also to prepare potassium phthalate buffer solution for pH calibration.

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

387.1 °F - Pensky-Martens closed cup

flash_point_c

197.3 °C - Pensky-Martens closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Certificados de análisis (COA)

Lot/Batch Number
0000370041
0000325000
MKCW2084
MKCW7100
0000370041

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Determination of standard pH values for potassium hydrogen phthalate reference buffer solutions in 10, 20, 50, 64 and 84.2 wt per cent methanol/water mixed solvents at temperatures from 283.15 to 313.15 K.
Mussini T, et al.
Electrochimica Acta, 28(11), 1593-1598 (1983)
2, 4, 6-Trinitrobenzoic acid as a primary standerd in acidimetry.
Smith GF and Wilkins DH.
Analytica Chimica Acta, 8, 209-216 (1953)
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Randi J Bertelsen et al.
Environmental health perspectives, 121(2), 251-256 (2012-11-21)
High-molecular-weight phthalates in indoor dust have been associated with asthma in children, but few studies have evaluated phthalate biomarkers in association with respiratory outcomes. We explored the association between urinary concentrations of phthalate metabolites and current asthma. In a cross-sectional
Martha M Téllez-Rojo et al.
The Science of the total environment, 461-462, 386-390 (2013-06-12)
Previous studies suggest that prenatal phthalate exposure affects neurodevelopment and behavior during the first years of life. To evaluate the effect of maternal urinary concentrations of phthalate metabolites during pregnancy on mental and psychomotor development in children 24-36 months of
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