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932361

Sigma-Aldrich

1,3,5-Tri[(3-pyridyl)-phen-3-yl]benzene

≥99% (HPLC)

Sinónimos:

TmPyPB

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About This Item

Fórmula empírica (notación de Hill):
C39H27N3
Número de CAS:
921205-03-0
Peso molecular:
537.65
MDL number:
MFCD16621131
UNSPSC Code:
12352005
NACRES:
NA.23

grade

sublimed grade

Quality Level

100

description

μe ≈ 1.0 x 10-3 cm2 V−1 s−1

assay

≥99% (HPLC)

loss

0.5% TGA, > 310 °C (weight loss)

mp

195-200 °C

transition temp

Tg >310 °C ((0.5% weight loss))

solubility

chloroform: soluble
dichloromethane: soluble

fluorescence

λem 353 nm in dichloromethane (PL)

orbital energy

HOMO 6.75 eV 
LUMO 2.75 eV 

λ

in dichloromethane

UV absorption

λ: 254 nm Amax

SMILES string

C1(C2=CC=CC(C3=CN=CC=C3)=C2)=CC(C4=CC=CC(C5=CN=CC=C5)=C4)=CC(C6=CC=CC(C7=CN=CC=C7)=C6)=C1

InChI

1S/C39H27N3/c1-7-28(34-13-4-16-40-25-34)19-31(10-1)37-22-38(32-11-2-8-29(20-32)35-14-5-17-41-26-35)24-39(23-37)33-12-3-9-30(21-33)36-15-6-18-42-27-36/h1-27H

InChI key

CINYXYWQPZSTOT-UHFFFAOYSA-N

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Application

1,3,5-Tri[(3-pyridyl)-phen-3-yl]benzene, also known as TmPyPB, is a solution-processable electron transport / hole blocking layer (ETL / HBL) material used in organic electronics. It has a μe around 1.0 x 10-3 cm2 V−1 s−1.
1,3,5-Tri[(3-pyridyl)phen-3-yl]benzene can be employed as a component in the synthesis of luminescent materials, including organic light-emitting diodes (OLEDs) or fluorescent dyes for sensing and imaging applications. It an be used as a building block or donor material in the active layer of Organic photovoltaics (OPV) devices.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Lot/Batch Number

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Huijun Liu et al.
Angewandte Chemie (International ed. in English), 57(30), 9290-9294 (2018-06-02)
Non-doped organic light-emitting diodes (OLEDs) possess merits of higher stability and easier fabrication than doped devices. However, luminescent materials with high exciton use are generally unsuitable for non-doped OLEDs because of severe emission quenching and exciton annihilation in neat films.
Meng Li et al.
Angewandte Chemie (International ed. in English), 57(11), 2889-2893 (2018-01-23)
Aromatic-imide-based thermally activated delayed fluorescent (TADF) enantiomers, (+)-(S,S)-CAI-Cz and (-)-(R,R)-CAI-Cz, were efficiently synthesized by introducing a chiral 1,2-diaminocyclohexane to the achiral TADF unit. The TADF enantiomers exhibited high PLQYs of up to 98 %, small ΔEST  values of 0.06 eV, as well
Wei Li et al.
Angewandte Chemie (International ed. in English), 58(2), 582-586 (2018-11-21)
To date, blue dual fluorescence emission (DFE) has not been realized because of the limited choice of chemical moieties and severe geometric deformation of the DFE emitters leading to strong intramolecular charge transfer (ICT) with a large Stokes shift in
Hui Wang et al.
Advanced materials (Deerfield Beach, Fla.), 26(30), 5198-5204 (2014-06-07)
Thermally activated delayed fluorescence emitters with small energy gap between the triplet and singlet (ΔEST ), TXO-PhCz and TXO-TPA, have been successfully synthesized by combining a hole-transporting TPA/PhCz moiety and an electron-transporting TXO moiety. Both compounds display efficient solid-state luminescence
Jia-Xiong Chen et al.
Angewandte Chemie (International ed. in English), 58(41), 14660-14665 (2019-07-18)
Developing red thermally activated delayed fluorescence (TADF) emitters, attainable for both high-efficient red organic light-emitting diodes (OLEDs) and non-doped deep red/near-infrared (NIR) OLEDs, is challenging. Now, two red emitters, BPPZ-PXZ and mDPBPZ-PXZ, with twisted donor-acceptor structures were designed and synthesized
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